Melamine process with a two-stage purification of melamine offgas
AssigneeCasale SA
InventorSimone Gamba
Life of this patent
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Abstract
A process for the synthesis of melamine including the purification of the offgas released by the synthesis of melamine by means of a first purification stage followed by a second purification stage (7); in the first purification stage (6) the offgas (3) is contacted with urea melt from the second stage (7) and with a recirculated urea melt (8, 9) containing ammonia and melamine precursors (5); in the second purification stage (7) the offgas from the first stage is contacted with fresh urea melt (15); said recirculated urea melt is withdrawn from bottom of the first stage and cooled in a shell and tube heat exchanger (11) to a temperature of not less than 165° C. preferably in the range 165° C. to 245° C. prior to reintroduction in said first stage.
Claims20
A process for the synthesis of melamine including the steps of:
- reacting a feed stream of urea melt under non-catalytic high pressure melamine synthesis conditions to generate a raw melamine product and an offgas comprising ammonia and carbon dioxide,
- subjecting said offgas to a purification process by washing the offgas with urea melt, to obtain a purified offgas and a urea melt containing ammonia and melamine precursors, wherein the purification process includes a first purification step performed in a first purification stage and a second purification step performed in a second purification stage,
- wherein said purification steps are carried out in sequence so that the offgas from the melamine synthesis is subject to the first purification step and the so obtained partially purified gas is further processed in the second purification step,
- wherein:
- during said first purification step, the offgas is contacted with urea melt comprising a recirculated urea melt containing ammonia and melamine precursors, said recirculated urea melt being withdrawn from the first stage and reintroduced in the same first stage,
- wherein said recirculated urea melt, before being reintroduced in the first stage, is cooled in a shell and tube heat exchanger to a temperature not less than 165° C.
Dependencies are inferred from the claim text.