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US 12,391,620 B2Granted
Batch mixtures containing pre-reacted inorganic particles and methods of manufacture of ceramic bodies therefrom
AssigneeCorning Incorporated
InventorsHuthavahana Sarma Kuchibhotla, Christophe Michel Remy, Patrick David Tepesch, Elizabeth Marie Vileno
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Abstract
A batch mixture comprising pre-reacted pseudobrookite particles consisting essentially of aluminum titanate and magnesium dititanate, a reactive alumina source, a reactive titania source, and a reactive silica source. Other batch mixtures and methods of manufacturing honeycomb extrudates and porous honeycomb bodies using the batch mixture are disclosed.
Claims26
A method of making a ceramic body, the method comprising:
- mixing together a batch mixture comprising a total amount of inorganic particles comprised of a first quantity of particles and a second quantity of particles, wherein the first quantity of particles comprises constituents capable of producing aluminum titanate via reactive sintering at one or more reactive sintering temperatures, wherein the first quantity of particles comprises a reactive alumina source, a reactive titania source, and a reactive silica source, and wherein the second quantity of particles comprises pre-reacted crystalline particles comprising aluminum titanate in an amount from 70 wt % to 99 wt % and magnesium dititanate in an amount from 1 wt % to 30 wt % relative to the total amount of inorganic particles, wherein the pre-reacted crystalline particles have a pseudobrookite type crystal structure and are stable with respect to the first quantity of particles at the one or more reactive sintering temperatures;
- shaping the batch mixture into a green ceramic body comprising the total amount of inorganic particles;
- and
- heating the green ceramic body at the one or more reactive sintering temperatures and for one or more times sufficient to cause the reactive alumina source, the reactive titania source, and the reactive silica source to reactively sinter and form the ceramic body with a predominant solid state phase comprising crystalline aluminum titanate having the pseudobrookite type crystal structure,
- wherein the pre-reacted crystalline particles present in the green ceramic body constitute less than or equal to 33 wt. % of the total amount of inorganic particles.
2 more elements
A method of making a ceramic body, the method comprising:
- mixing together a batch mixture comprising a total amount of inorganic particles comprised of a first quantity of particles and a second quantity of particles, wherein the first quantity of particles comprises constituents capable of producing aluminum titanate via reactive sintering at one or more reactive sintering temperatures, wherein the first quantity of particles comprises a reactive alumina source, a reactive titania source, and a reactive silica source, and wherein the second quantity of particles comprises pre-reacted crystalline particles comprising aluminum titanate in an amount from 70 wt % to 99 wt % relative to the total amount of inorganic particles in the batch mixture, wherein the pre-reacted crystalline particles have a pseudobrookite type crystal structure and are stable with respect to the first quantity of particles at the one or more reactive sintering temperatures;
- shaping the batch mixture into a green ceramic body, the pre-reacted crystalline particles present in the green ceramic body in an amount from equal to or greater than 0.01 wt. % to equal to or less than 5.0 wt. % of the total amount of inorganic particles in the green ceramic body;
- heating the green ceramic body at the one or more reactive sintering temperatures and for one or more times sufficient to cause the reactive alumina source, the reactive titania source, and the reactive silica source to reactively sinter and form the ceramic body with a solid state phase comprising crystalline aluminum titanate having the pseudobrookite type crystal structure and in an amount from 63 wt % to 84 wt %;
- and
- wherein a CTE of the ceramic body is less than or equal to 5.0×10−7/° C. over a temperature range from 25° C. to 800° C.
2 more elements
Dependencies are inferred from the claim text.