Method for producing bromine pentafluoride
AssigneeResonac Corporation
InventorKazuma Matsui
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Abstract
There is provided a method for producing high-purity bromine pentafluoride while leaving a less amount of an unreacted fluorine gas. The method for producing bromine pentafluoride includes a reaction step of feeding a bromine-containing compound, which is at least one of a bromine gas and bromine trifluoride, and a fluorine gas to a reactor to give a (fluorine atom):(bromine atom) molar ratio, that is, F/Br of 3.0 or more and 4.7 or less and reacting the bromine-containing compound and the fluorine gas to each other to obtain a reaction mixture containing bromine pentafluoride and bromine trifluoride; and a separation step of separating bromine pentafluoride and bromine trifluoride in the reaction mixture from each other.
Claims19
A method for producing bromine pentafluoride, comprising:
- a reaction step of feeding a bromine-containing compound, the bromine-containing compound being at least one of a bromine gas and bromine trifluoride, and a fluorine gas to a reactor to give a (fluorine atom):
- (bromine atom) molar ratio, that is, F/Br of 3.0 or more and 4.7 or less and reacting the bromine-containing compound and the fluorine gas to each other to obtain a reaction mixture containing bromine pentafluoride and bromine trifluoride;
- and
- a separation step of separating bromine pentafluoride and bromine trifluoride in the reaction mixture from each other;
- wherein the separation step includes a cooling step of cooling and separating the reaction mixture into a gas component containing bromine pentafluoride and a liquid-solid component containing bromine trifluoride;
- and
- wherein the cooling step includes a first cooling step including cooling the reaction mixture in a temperature range of−20° C. or more to not more than a melting temperature of the bromine trifluoride to collect the bromine trifluoride, and a second cooling step including cooling the bromine pentafluoride in the reaction mixture in a temperature range of−80° C. or more to not more than melting temperature of the bromine pentafluoride to collect the bromine pentafluoride.
Dependencies are inferred from the claim text.