Back to results
US 12,384,887 B2Granted
Epoxy functionalized poly(aryl ether sulfones) copolymers
AssigneeSolvay Specialty Polymers USA, LLC
InventorsKamlesh Nair, Joel Pollino
Life of this patent
Estimating the term…
Abstract
The invention pertains to a side-chain epoxy-functionalized copolymer (P1) and to the process for preparing this copolymer (P1). The present invention also pertains to the use of the copolymer (P1) in the preparation of a membrane, a composite material or a coating. The present invention also relates to a resin composition comprising at least the copolymer (P1) according to the present invention.
Claims14
A copolymer (P1) comprising:
- recurring units (RP1) of formula (M):
- and
- recurring units (R*P1) of formula (N):
- wherein
- each R1 is independently selected from the group consisting of a halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali metal sulfonate, alkaline earth metal sulfonate, alkyl sulfonate, alkali metal phosphonate, alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium;
- each i is independently selected from 0 to 4;
- GN is selected from the group consisting of the following formulas:
- each k is independently selected from 0 to 4;
- each j is independently selected from 3 to 7;
- T and Q are independently selected from the group consisting of a bond, —O—;
- —SO2—;
- —S—;
- —C(O)—;
- —C(CH3)2—;
- —C(CF3)2—;
- —C(═CCl2)—;
- —C(CH3)(CH2CH2COOH)—;
- —N═N—;
- —RaC═CRb—;
- —(CH2)m—;
- —(CF2)m—;
- a linear aliphatic divalent group of up to 6 carbon atoms, a branched aliphatic divalent group of up to 6 carbon atoms;
- and combinations thereof, in which each Ra and Rb, independently of one another, is hydrogen, a C1-C12-alkyl, a C1-C12-alkoxy, or a C6-C18-aryl group;
- and in which m is an integer from 1 to 6.
21 more elements
A process for preparing copolymer (P1) comprising at least partially epoxidizing a copolymer (P0) comprising:
- recurring units (RP0) of formula (M):
- and
- recurring units (R*P0) of formula (P):
- wherein
- each R1 is independently selected from the group consisting of a halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali metal sulfonate, alkaline earth metal sulfonate, alkyl sulfonate, alkali metal phosphonate, alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium;
- each i is independently selected from 0 to 4;
- GP is selected from the group consisting of the following formulas:
- each k is independently selected from 0 to 4,
- T and Q are independently selected from the group consisting of a bond, —O—;
- —SO2—;
- —S—;
- —C(O)—;
- —C(CH3)2—;
- —C(CF3)2—;
- —C(═CCl2)—;
- —C(CH3)(CH2CH2COOH)—;
- —N═N—;
- —RaC═CRb—;
- —(CH2)m—;
- —(CF2)m—;
- a linear aliphatic divalent group of up to 6 carbon atoms, a branched aliphatic divalent group of up to 6 carbon atoms;
- and combinations thereof, in which each Ra and Rb, independently of one another, is hydrogen, a C1-C12-alkyl, a C1-C12-alkoxy, or a C6-C18-aryl group, and in which m is an integer from 1 to 6.
19 more elements
Dependencies are inferred from the claim text.