Galvannealed steel sheet
AssigneeArcelorMittal
InventorsDavid Zapico Alvarez, Florence Bertrand, Joris Giroux
Life of this patent
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Abstract
A galvannealed steel sheet obtainable by a method including the provision of a specific steel sheet, a recrystallization annealing with specific heating, soaking and cooling sub-steps using an inert gas, a hot-dip galvanizing and an alloying treatment, wherein the zinc coating is alloyed through diffusion of the iron from the steel sheet such that the zinc coating includes from 5 to 15% by weight of Fe, oxides including FeO, Mn2SiO4 and MnO, the balance being zinc, the steel sheet including internal oxides including FeO, Mn2SiO4 and MnO in the steel sheet.
Claims18
A galvannealed steel sheet obtainable by a method comprising:
- A. providing a steel sheet having the following chemical composition in weight percent:
- 0.05≤C≤0.20%,
- 1.5≤Mn≤3.0%,
- 0.10≤Si≤0.45%,
- 0.10≤Cr≤0.60%,
- 0≤Al≤0.20%,
- 0≤V<0.005%,
- 0≤P<0.04%,
- 0≤Nb≤0.05%,
- 0≤B≤0.003%,
- 0≤Mo≤0.20%,
- 0≤Ni≤0.1%,
- 0≤Ti≤0.06%,
- 0≤S≤0.01%
- 0≤Cu≤0.1%,
- 0≤Co≤0.1%,
- 0≤N≤0.01%,
- a remainder of the composition being made of iron and inevitable impurities resulting from processing;
- B. recrystallization annealing the steel sheet in a full radiant tube furnace comprising a heating section, a soaking section, and a cooling section, and optionally an equalizing section, the recrystallization annealing including the following sub-steps:
- i. heating the steel sheet from ambient temperature to a temperature T1 between 700 and 900° C. in the heating section having an atmosphere A1 including from 0.1 to 15% by volume of H2 and an inert gas with a dew point DP1 is between −18° C. and +8° C.,
- ii. soaking the steel sheet from T1 to a temperature T2 between 700 and 900° C. in the soaking section having an atmosphere A2 identical to A1 with a dew point DP2 equal to DP1, and
- iii. cooling the steel sheet from T2 to T3 between 400 and 700° C. in the cooling section having an atmosphere A3 including from 1 to 30% H2 by volume and an inert gas with a dew point DP3 is below or equal to −30° C., and
- iv. optionally, equalizing the steel sheet from a temperature T3 to a temperature T4 between 400 and 700° C. in the equalizing section having an atmosphere A4 including from 1 to 30% H2 by volume and an inert gas with a dew point DP4 is below or equal to −30° C.,
- C. hot-dip galvanizing of the annealed steel sheet in a zinc bath;
- and
- D. alloying the galvanized annealed steel sheet, the alloying performed at a temperature T5 between 460 and 600° C. during a time t5 between 1 and 45 seconds;
- wherein the zinc coating is alloyed through diffusion of the iron from the steel sheet such that the zinc coating includes from 5 to 15% by weight of Fe, oxides including FeO, Mn2SiO4 and MnO, the balance being zinc, the steel sheet including internal oxides including FeO, Mn2SiO4 and MnO in the steel sheet.
Dependencies are inferred from the claim text.