Process for producing 1-(4-isobutylphenyl)ethanol by hydrogenation of 1-(4-isobutyl-phenyl)ethanone in the presence of a catalyst composition comprising copper
AssigneeBASF SE
InventorsAlbert Werner, Annebart Wentink, Simon Kokolakis, Andreas Weickgenannt, Rolf Pinkos
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Abstract
Described is a process for producing 1-(4-isobutylphenyl)ethanol by reacting 1-(4-isobutyl-phenyl)ethanone with hydrogen in the presence of a catalyst composition comprising cop-per and one or more metals other than copper, and a use of a respective composition and/or of a pre-composition, the pre-composition comprising a mixture of oxides of copper and oxides of one or more metals other than copper, in a catalytic hydrogenation process for producing 1-(4-isobutylphenyl)ethanol from 1-(4-isobutylphenyl)ethanone.
Claims15
A process for producing 1-(4-isobutylphenyl) ethanol comprising:
- S3) reacting 1-(4-isobutylphenyl)ethenone with hydrogen in the presence of a catalyst composition comprising copper and one or more metal other than copper,
- wherein the catalyst composition comprises
- c1) the copper in a total amount in a range of from 65 mass-% to 92.5 mass-%, relative to the total mass of metals present in the catalyst composition;
- c2) a carrier component comprising one or more substance selected from the group consisting of silicon and silicon compounds, wherein a total amount of silicon in the catalyst composition, relative to the total mass of copper present in the catalyst composition, is in a range of from 3.5 mass-% to 15.0 mass-%;
- and
- c3) manganese in a total amount in a range of from 0.75 mass-% to 3.15 mass-%, relative to the total mass of metals present in the catalyst composition;
- and
- one or more metal selected from the group consisting of sodium and calcium, wherein a total amount of the one or more metal selected from the group consisting of sodium and calcium in the catalyst composition, relative to the total mass of metals present in the catalyst composition, is in a range of from 4.5 mass-% to 15.0 mass-%;
- and
- wherein the catalyst composition has a molar ratio of copper:aluminum of ≥10.
Dependencies are inferred from the claim text.