Fiber-blended heterophasic copolymer for additive-manufacture feedstock
AssigneeBraskem America, Inc.
InventorsJacob Fallon, Alexandre Di Pintor Da Luz, Michelle Sing, Kevin Herrington
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Abstract
The invention relates to an additive-manufacture feedstock, comprising a heterophasic copolymer having a melt flow rate of from 0.1 to 150 g/10 min (230° C./2.16 kg), measured according to ASTM D 1238, and a fiber blended in the heterophasic copolymer. The first-fiber-blended heterophasic copolymer, when in the form of a printed article, exhibits a minimized warpage. The invention also relates to methods of making the additive-manufacture feedstock and methods of 3D printing using the additive-manufacture feedstock in various forms.
Claims27
An additive-manufacture feedstock, comprising:
- a heterophasic copolymer having a melt flow rate of from 0.1 to 150 g/10 min (230° C./2.16 kg), measured according to ASTM D 1238, and
- a first-fiber blended in the heterophasic copolymer,
- wherein:
- the first-fiber is present in the additive-manufacture feedstock in an amount of from 1.0 to 40 wt %, relative to 100 wt % of the additive-manufacture feedstock, and
- the first-fiber-blended heterophasic copolymer, when in the form of a printed article, exhibits a warpage resistance rating of at most 1 mm, measured according to the following equation and 48 hours after printing the printed article:
- warpage
-
- resistance
-
- rating
- =
- ∑
- i
- =
- 1
- N
- WS
- i
- N
- wherein:
- Σi=1N WSi sums the values of WSi, starting at WS1 and ending with WSN,
- N is the total number of printed articles measured for warpage resistance rating evaluation,
- i is a ith printed article measured,
- WSi=Max (X1,X2,X3,X4)i−Min (Y1,Y2,Y3,Y4)i for a ith printed article measured,
- X1, X2, X3, and X4, respectively, represent a height of a first central edge, a height of a second central edge, a height of a third central edge, and a height of a fourth central edge, of the ith printed article measured,
- Y1, Y2, Y3, and Y4, respectively, represent a height of a first corner edge, a height of a second corner edge, a height of a third corner edge, and a height of a fourth corner edge, of the ith printed article measured,
- Max (X1,X2,X3,X4)i represents the maximum value of X1, X2, X3, and X4, for the ith printed article measured, and
- Min (Y1,Y2,Y3,Y4)i represents the minimum value of Y1, Y2, Y3, and Y4, for the ith printed article measured,
- wherein each printed article measured for warpage resistance rating evaluation is a 60 mm×60 mm×60 mm cubic box, each side of the cubic box having a thickness of 1 mm.
Dependencies are inferred from the claim text.