Silver powder, method for producing same, and conductive resin composition
AssigneeMitsui Mining & Smelting Co., Ltd.
InventorKentaro Ochi
Life of this patent
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Abstract
A silver powder containing dendrite silver particles is provided. The dendrite silver particles are in a dendrite shape having one trunk and a plurality of branches branching from the trunk. The thickness of the trunk of the dendrite silver particles is from 10 to 280 nm. The number of the branches per length of the trunk is from 6 to 30 branches/μm. The percentage by number of the dendrite silver particles in the whole of silver particles is 50 N % or more. This silver powder is produced by reducing silver ions through electrolysis of an electrolyte solution containing silver ions and hydantoin or a derivative thereof.
Claims9
A silver powder comprising silver particles including dendrite silver particles, each of the dendrite silver particles being in a dendrite shape having only a single trunk and a plurality of branches branching from the single trunk,
- wherein a thickness of the single trunk is from 10 to 280 nm, and a length of the single trunk is from 0.5 to 10.0 μm,
- the number of the plurality of branches per length of the single trunk is from 6 to 30 branches/μm,
- the plurality of branches directly branch from the single trunk, and
- the percentage by number of the dendrite silver particles in the whole of the silver particles is 50 N % or more,
- the silver powder has a shrinkage rate of 0.3% or more, and the shrinkage rate is defined under the following conditions:
- 0.5 g of the silver powder is placed in a measurement fitting, to which a first load is applied, to obtain a sample;
- the sample is disposed on a thermo-mechanical analyzer, and a temperature of the sample is increased under a second load from 25° C. to 800° C. at a rate of 10° C./min in a mixed atmosphere of nitrogen and hydrogen;
- and
- an absolute value of a negative coefficient of expansion at 150° C. is defined as the shrinkage rate, and
- the silver powder has a crystallite size of from 10 to 49 nm.
Dependencies are inferred from the claim text.