Method for producing carbonate derivative
AssigneesNational University Coporation Kobe University, Mitsubishi Gas Chemical Company, Inc.
InventorAkihiko Tsuda
Life of this patent
Estimating the term…
Abstract
The objective of the present invention is to provide a method for producing a polycarbonate safely and efficiently even without using a base. The method for producing a carbonate derivative according to the present invention is characterized in comprising the step of irradiating a high energy light to a composition comprising the halogenated methane and the hydroxy group-containing compound in the presence of oxygen, wherein a molar ratio of a total usage amount of the hydroxy group-containing compound to 1 mole of the halogenated methane is 0.05 or more.
Claims5
A method for producing a carbonate derivative,
- the method consisting of an optional step of stirring a liquid composition comprising a halogenated methane and a hydroxy group-containing compound without irradiating a high energy light, and a step of irradiating the high energy light to the liquid composition in the presence of oxygen to produce the carbonate derivative, and optionally repeating the optional step of stirring and the step of irradiating,
- wherein the liquid composition does not comprise a base,
- wherein a molar ratio of a total usage amount of the hydroxy group-containing compound to 1 mole of the halogenated methane is 0.1 or more,
- wherein the hydroxy group-containing compound is represented by the following formula (i) and the carbonate derivative is a linear carbonate derivative represented by the following formula (I), or
- the hydroxy group-containing compound is represented by the following formula (ii) and the carbonate derivative is a carbonate derivative comprising a unit represented by the following formula (II-1) or a cyclic carbonate derivative represented by the following formula (II-2):
- R1—OH (i)
- HO—R2—OH (ii)
- R1—O—C(═O)—O—R1 (I)
- [—O—R2—O—C(═O)—] (II-1)
- wherein
- R1 is a monovalent C1-200 organic group optionally comprising a hetero atom,
- R2 is a divalent C1-200 organic group optionally comprising a hetero atom.
Dependencies are inferred from the claim text.