Targeted corrosion inhibitor for marine reinforced concrete, and preparation and application thereof
AssigneesHenan academy of sciences, Institute of Chemistry Co. Ltd Henan Academy of Sciences
InventorsWeihua Li, Mengzhu Chen, Haibing Zheng
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Abstract
A targeted corrosion inhibitor for marine reinforced concrete, and a preparation and application thereof. The targeted corrosion inhibitor is a nano silver-loaded nitrite-intercalated layered double hydroxide. The targeted corrosion inhibitor is prepared based on interlayer ion exchangeability of layered double hydroxides and specific recognition of Ag+ to chloride ions.
Claims7
A method for preparing a targeted corrosion inhibitor, the targeted corrosion inhibitor being a nano silver-loaded nitrite-intercalated Ca—Al layered double hydroxide,
- the method comprising:
- (S1) dissolving sodium carbonate, calcium hydroxide, sodium metaaluminate, silver nitrate and sodium nitrite in boiling water, respectively, to obtain a first solution, a second solution, a third solution, a fourth solution and a fifth solution;
- (S2) mixing the first solution, the second solution and the third solution followed by pH adjustment to obtain a reaction solution;
- and stirring the reaction solution;
- (S3) subjecting the reaction solution to a hydrothermal reaction followed by vacuum filtration to obtain a first filter cake;
- and washing, drying and grinding the first filter cake to obtain a Ca-layered double hydroxide (Ca-LDH);
- (S4) calcining the Ca-LDH obtained in step (S3) to obtain a Ca-layered double oxide (Ca-LDO);
- (S5) dissolving the Ca-LDO in the fourth solution followed by pH adjustment, stirring and vacuum filtration to obtain a second filter cake;
- and washing and drying the second filter cake to obtain an Ag/Ca-layered double oxide (Ag/Ca-LDO);
- and
- (S6) dissolving the Ag/Ca-LDO in the fifth solution followed by stirring at room temperature for 24-48 h, and vacuum filtration to obtain a third filter cake;
- and washing and drying the third filter cake to obtain the targeted corrosion inhibitor.
Dependencies are inferred from the claim text.