Continuous process for iodide cutting and autogenous fusion and separation of iodine, and device for carrying out the process
AssigneeUniversidad de Santiago de Chile
InventorRicardo Emilio Vega Viveros
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Abstract
The present invention relates to a process for obtaining and refining elemental iodine contained in an iodide solution, which specifically comprises the steps of iodide cutting, and iodine melting, which take place simultaneously by reacting the preheated iodide solution with an oxidizing agent for directly producing elemental molten iodine, without passing iodine through a crystalline state; and the step of separating elemental molten iodine from spent melt water by liquid-liquid separation; carrying out all these steps in a single system operated in continuous regime.
Claims15
A continuous process for obtaining and refining elemental iodine contained in an iodide solution, specifically for the steps of iodide cutting with an oxidizing agent, and iodine fusion, and separation, characterized in that:
- the iodide cutting step comprises reacting a preheated iodide solution flow with an oxidizing agent flow to directly produce elemental molten iodine;
- the elemental molten iodine separation from the spent melt water occurs by liquid-liquid separation,
- iodine cutting occurs without the passage of iodine through the crystalline state, in those said steps are carried out in a single system:
- the rapid shear reaction takes place almost entirely in an in-line mixer, just before entering the liquid-liquid separator, which provides sufficient time for completion and separation of the liquid iodine from the spent brine.
A system for carrying out a continuous process for obtaining and refining elemental iodine contained in an iodide solution, characterized in that it comprises:
- an iodide solution heater,
- a feeder for the oxidizing agent flow and a feeder for the iodide solution flow, which simultaneously lead both flows to a mixing point in an in-line mixer, where iodide cutting takes place, producing practically instantaneously elemental liquid iodine and spent solution, and
- a separator reactor located immediately downstream of the mixing point, that allows to complete the cutting reaction and carry out the separation of the streams of the refined molten iodine and the depleted solution.
Dependencies are inferred from the claim text.