Comb polymers as blocking additives for swelling clays
AssigneeSika Technology AG
InventorsUlf Velten, Jürg Weidmann, Lukas Frunz, Patrick Juilland
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Abstract
A method for inerting a swellable clay and/or for reducing or inhibiting adverse effects of swellable clays on the effectiveness of dispersants in mineral binder compositions, includes adding a comb polymer to a mineral binder composition. The comb polymer includes: at least one poly(alkylene oxide) side chain-bearing monomer unit without ionic groups, optionally at least one cationic monomer unit, optionally at least one anionic monomer unit, and optionally, at least one non-ionic monomer unit.
Claims5
A method for inerting a swellable clay and/or for reducing or inhibiting adverse effects of swellable clays on the effectiveness of dispersants in mineral binder compositions, comprising adding a comb polymer to a mineral binder composition,
- wherein the comb polymer comprises:
- at least one poly(alkylene oxide) side chain-bearing monomer unit M1 without ionic groups,
- optionally at least one anionic monomer unit MA,
- optionally, at least one non-ionic monomer unit M3,
- wherein the comb polymer, with respect to a total number of monomer units present in the comb polymer, comprises:
- 98-100 mol-%, of the at least one poly(alkylene oxide) side chain-bearing monomer unit M1,
- 0 mol-%, of a cationic monomer unit MC,
- 0-1 mol-%, of the at least one anionic monomer unit MA, and
- 0-1 mol-%, of the at least one non-ionic monomer unit M3, and
- wherein the side chain-bearing monomer unit M1 includes a structure of formula I
- wherein
- R1, and R2, in each case independently, are H or an alkyl group having 1 to 5 carbon atoms,
- R3, in each case independently, is H, an alkyl group having 1 to 5 carbon atoms, or a group with formula
- m and m″=0, 1 or 2,
- p and p″=0,
- X and X″, in each case independently, is —O— or —NH—,
- R4 and R4″ is a group of the formula -[AO]n—Ra
- where A is a C2- to C4-alkylene, Ra is H, a C1- to C20-alkyl group, -cycloalkyl group or -alkylaryl group,
- and n=2-250.
Dependencies are inferred from the claim text.