Sintered alumina-zirconia balls
AssigneeSaint-Gobain Centre de Recherches et d'Etudes European
InventorEmmanuel Nonnet
Life of this patent
Estimating the term…
Abstract
Sintered bead that has a crystalline composition, as percentages by weight based on the total weight of the crystalline phases: zircon<25%; 50%≤cubic zirconia+tetragonal zirconia≤95%, the cubic zirconia content being greater than 50%, the cubic zirconia content being the (cubic zirconia/(cubic zirconia+tetragonal zirconia) ratio by weight); 0≤monoclinic zirconia≤(10−0.2*tetragonal zirconia) %; 5%≤corundum≤50%; crystalline phases other than zircon, cubic zirconia, tetragonal zirconia, monoclinic zirconia and corundum<10%; and the following chemical composition, as percentages by weight based on the oxides: 34%≤ZrO2+HfO2, ZrO2+HfO2 being the remainder to 100%; HfO2≤4.0%; 0.5%≤SiO2≤14.1%; 4.5%≤Al2O3≤49.6%; 2.75%≤Y2O3≤22.8%; MgO≤5%; CaO≤2%; oxides other than ZrO2, HfO2, SiO2, Al2O3, MgO, CaO and Y2O3<5.0%.
Claims20
A sintered bead exhibiting:
- the following crystalline composition, as percentages by weight based on the total weight of the crystalline phases and for a total of 100%:
- zircon<25%;
- 50%≤cubic zirconia+tetragonal zirconia≤95%, the cubic zirconia content being greater than 50%, the cubic zirconia content being the (cubic zirconia/(cubic zirconia+tetragonal zirconia) ratio by weight);
- 0≤monoclinic zirconia≤(10−0.2*tetragonal zirconia) %;
- 5%≤corundum≤50%;
- crystalline phases other than zircon, cubic zirconia, tetragonal zirconia, monoclinic zirconia and corundum<10%;
- the following chemical composition, as percentages by weight based on the oxides:
- 34%≤ZrO2+HfO2, ZrO2+HfO2 being the remainder to 100%;
- HfO2≤4.0%;
- 0.5%≤SiO2≤14.1%;
- 4.5%≤Al2O3≤49.6%;
- 2.75%≤Y2O3≤22.8%;
- MgO≤5%;
- CaO≤2%;
- oxides other than ZrO2, HfO2, SiO2, Al2O3, MgO, CaO and Y2O3<5.0%,
- “stabilized zirconia” meaning an assembly consisting of said tetragonal zirconia and said cubic zirconia.
The manufacturing process as claimed in 19, in which one or more of said powder of zirconia stabilized with Y2O3, corundum powder, silica powder, cordierite powder, and clay powder is/are replaced, at least partially, by equivalent powders which result, in said beads, in the same constituents, in the same amounts, with the same crystallographic phases.
Dependencies are inferred from the claim text.