Interference resistant solid state reference electrode
AssigneeCommonwealth Scientific and Industrial Research Organisation
InventorsDavid Simon Macedo, Mikko Kalevi Vepsäläinen
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Abstract
The invention provides a solid state reference electrode comprising: a reference element in ionic communication with a composite, the composite comprising a water-permeable polymeric matrix loaded with a solid inorganic salt comprising a reference anion; an electrode surface for contacting an analyte; and a solid ion-exchange material located between the electrode surface and the reference element, the solid ion-exchange material comprising one or more non-interfering ions, wherein in use the solid ionexchange material immobilises one or more interfering ions, when present in solution in the analyte, by exchange with the noninterfering ions.
Claims19
A solid state reference electrode comprising:
- a reference element in ionic communication with a composite, the composite comprising an electrically insulating water-permeable polymeric matrix loaded with a solid inorganic salt comprising a reference anion, wherein the solid inorganic salt is sufficiently soluble in water that hydration of the composite will produce a constant saturation solution concentration of the reference anion at the reference element, and wherein the reference anion is capable of participating in a desired redox half-reaction at the reference element to provide a reference potential;
- an electrode surface for contacting an analyte;
- and
- a solid ion-exchange material located between the electrode surface and the reference element, the solid ion-exchange material comprising one or more non-interfering ions,
- wherein the reference element is electrically insulated from at least a portion of the solid ion-exchange material, and
- wherein the solid ion-exchange material comprises an ion exchange resin or a metal salt, and is configured to immobilize one or more interfering ions, when present in solution of the analyte, by exchange with the one or more non-interfering ions.
Dependencies are inferred from the claim text.