Electro-optic polymer
AssigneeNational Institute of Information and Communications Technology
InventorsAkira Otomo, Isao Aoki, Toshiki Yamada, Chiyumi Yamada
Life of this patent
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Abstract
The present invention provides an electro-optic polymer (EO polymer) comprising an electro-optic molecule (EO molecule) and a base polymer. The EO polymer of the present invention has good performance over the entire optical communication wavelength range and therefore can preferably be used for the production of optical modulators, optical switches, optical transceivers, optical phased arrays, LiDAR (light detection and ranging) devices, electric field sensors, terahertz wave generators and detectors, etc.
Claims15
An electro-optic polymer (EO polymer) comprising an electro-optic molecule (EO molecule) and a base polymer, the EO molecule having a structure in which a π-electron donor and a π-electron acceptor are conjugated via a π-conjugation bridge,
- the EO polymer having an electro-optic coefficient (EO coefficient) of 30 pm/V or more and a figure of merit (FOM) of 10×10−6 cm/dBV or more in an entire optical communication wavelength range of 1260 nm to 1625 nm,
- the FOM being defined by the following formula:
- FOM
- =
- n
- 3
-
- r
- a
- max
-
- λ
-
- [
- 1
-
- 0
- -
- 6
-
-
- cm
-
- /
-
- dBV
- ]
- [
- Math
- .
-
- 1
- ]
- wherein n indicates a refractive index, r indicates an EO coefficient, amax indicates a maximum absorption coefficient in a wavelength range of interest, and λ indicates a wavelength,
- wherein the EO molecule is a compound represented by the following formula (1):
- wherein
- RD1a, RD2a, and RD3a independently represent a hydrogen atom, an alkyl group, an alkoxy group, an aryloxy group, an aralkyloxy group, a silyloxy group, an alkenyloxy group, an alkynyloxy group, a hydroxy group, —R1—OH wherein R1 is a hydrocarbon group, —OR2—OH wherein R2 is a hydrocarbon group, —OC(═O)R3 wherein R3 is a hydrocarbon group, an amino group, —R4—NH2 wherein R4 is a hydrocarbon group, a thiol group, —R5—SH wherein R5 is a hydrocarbon group, —NCO, or —R6—NCO wherein R6 is a hydrocarbon group, and RD1a, RD2a, and RD3a each may have one or more identical or different substituents;
- RD4a and RD5a independently represent a hydrogen atom, an alkyl group, a haloalkyl group, an acyloxyalkyl group, a silyloxyalkyl group, —R1—OH wherein R1 is a hydrocarbon group, —R4—NH2 wherein R4 is a hydrocarbon group, an aryl group, —R5—SH wherein R5 is a hydrocarbon group, or —R6—NCO wherein R6 is a hydrocarbon group, and RD4a and RD5a each may have one or more identical or different substituents;
- X represents a linking group;
- RA1a and RA2a independently represent a hydrogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, an alkoxy group, an aryl group, a hydroxy group, —R1—OH wherein R1 is a hydrocarbon group, —OR2—OH wherein R2 is a hydrocarbon group, an amino group, —R4—NH2 wherein R4 is a hydrocarbon group, a thiol group, —R5—SH wherein R5 is a hydrocarbon group, —NCO, or —R6—NCO wherein R6 is a hydrocarbon group, and RA1a and RA2a each may have one or more identical or different substituents, and
- at least one of RA1a and RA2a is a substituent selected from the group consisting of an aryl group having a halogen atom, an aryl group having a haloalkyl group, and an aryl group having an aryl group optionally having a halogen atom;
- and
- wherein X in formula (1) is represented by the following formula (B-I)
- wherein
- RB1 and RB2 independently represent a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, a haloalkyl group, an aralkyl group, an aryloxy group, an aralkyloxy group, a hydroxy group, —R1—OH wherein R1 is a hydrocarbon group, —OR2—OH wherein R2 is a hydrocarbon group, an amino group, —R4—NH2 wherein R4 is a hydrocarbon group, a thiol group, —R5—SH wherein R5 is a hydrocarbon group, —NCO, or —R6—NCO wherein R6 is a hydrocarbon group, RB1 and RB2 each may have one or more identical or different substituents, and RB1 and RB2 may form a ring together with the two carbon atoms to which they are bound,
- π1 and π2 are each a structure represented by the following formula (B-IV):
- wherein n represents an integer of 1.
Dependencies are inferred from the claim text.