Waterborne, UV curable coating composition for easy-clean coatings
AssigneeAkzo Nobel Coatings International B.V.
InventorsZheng Shi, Quan James Huang, Puxin Fang, Hong Lin, Junbiao Lu
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AssigneeAkzo Nobel Coatings International B.V.
InventorsZheng Shi, Quan James Huang, Puxin Fang, Hong Lin, Junbiao Lu
Estimating the term…
The invention relates to the synthesis of a carboxyl-functional, unsaturated polyurethane containing a perfluoropolyether block, which can be used as an easy clean additive in preparation of a waterborne, UV curable coating composition. The polyurethane can be prepared by a method comprising the following steps: a) subjecting a hydroxy-terminated perfluoropolyether A to a reaction with a molar excess of polyisocyanate B to obtain an isocyanate-functional urethane C, b) adding a carboxyl-functional polyol D to the reaction mixture, c) adding OH— functional (meth)acrylate monomer E to the reaction mixture, wherein steps (b) and (c) can be performed in any order, and d) neutralizing the reaction product with a neutralizer F. The resulting coating has easy clean and anti-stain properties.
A waterborne, UV curable coating composition, comprising an aqueous dispersion of a polyurethane and at least one non-fluorinated polymer different from the polyurethane, wherein the polyurethane is present as an additive in an amount 0.1-5 wt. % based on resin solids of the coating composition, and wherein the polyurethane is a carboxyl-functional, unsaturated polyurethane containing a perfluoropolyether block, said polyurethane having a molecular weight Mn in the range from 1,000 to 5,000 determined by gel permeation chromatography with a polystyrene standard and tetrahydrofuran as the mobile phase, said polyurethane prepared by a method comprising the following steps:
Dependencies are inferred from the claim text.