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US 12,308,239 B2Granted
Semiconductor structure etching solution and method for fabricating a semiconductor structure using the same etching solution
AssigneeTaiwan Semiconductor Manufacturing Company, Ltd.
InventorChung-Chieh Lee
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Abstract
The present disclosure provides an etching solution, including an ionic strength enhancer having an ionic strength greater than 10−3 M in the etching solution, wherein the ionic strength enhancer includes Li+, Na+, K+, Mg2+, Ca2+, N(CH3)+, or N(C2H5)4+, a solvent, and an etchant.
Claims20
A method of forming a trench having an opening smaller than 20 nm, comprising:
- preparing an etching solution including an ionic strength enhancer, wherein the ionic strength of the ionic strength enhancer is greater than 10−3 M in the etching solution, and the ionic strength enhancer includes alkali cation and anion selected from F−, Cl−, Br−, I−, SO42−, or HCO3−;
- and
- applying the etching solution to a substrate having a semiconductor material thereby forming the trench in the substrate.
A method of removing a stripe having a line width smaller than 20 nm in a semiconductor structure, the method comprising:
- forming a sidewall spacer surrounding the stripe;
- preparing an etching solution by applying an ionic strength enhancer to an etchant, wherein the ionic strength enhancer has a molar concentration in a range from about 10−3 M to about 10 M in the etching solution and includes at least one of Li+, Na+, K+, Mg2+, Ca2+, N(CH3)+, and N(C2H5)4+;
- and
- applying an etching solution to the stripe.
1 more element
A method for silicon removal enhancement during forming a semiconductor structure, comprising:
- combining an ionic strength enhancer, a solvent and an etchant to form an etching solution, wherein the ionic strength enhancer has an ionic strength greater than 10−3 M in the etching solution, the solvent comprising at least one of isopropanol, acetone, acetic acid, ethyl acetate, or super critical carbon dioxide;
- forming at least one silicon stripe with a width narrower than 20 nm;
- covering at least a sidewall of the silicon stripe with a dielectric material;
- and
- applying the etching solution to remove the silicon stripe thereby exposing a sidewall of the dielectric material and forming a trench having an average width substantially similar to a width of the silicon stripe.
2 more elements
Dependencies are inferred from the claim text.