Polycarbonate resin composition
AssigneeMitsubishi Gas Chemical Company, Inc.
InventorsKohei Yoshiya, Noriyoshi Ogawa
Life of this patent
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Abstract
The present application provides a polycarbonate-based coating resin composition having high adhesiveness, more specifically provides a polycarbonate resin composition that contains not less than 0.1 parts by mass of a polyisocyanate compound and 100 parts by mass of a terminal-modified polycarbonate resin (A) having a structural unit (2) and a terminal structure represented by structural formula (1). [In formula (1) and formula (2), R1-R7, X, Y, Z, and a are as described in the description.]
Claims18
A resin solution comprising a polycarbonate resin composition and a non-halogenated organic solvent, the polycarbonate resin composition comprising:
- 100 parts by mass of a terminal-modified polycarbonate resin (A) having a terminal structure represented by structural formula (1) below and a structural unit (2) below;
- and
- not less than 0.1 parts by mass of a polyisocyanate compound,
- (in formula (1),
- R1 represents an optionally substituted C1-C20 alkylene group or C2-C20 alkenylene group,
- R2 and R3 each independently represent hydrogen, a C1-C20 alkyl group, a C1-C10 alkoxy group or a C6-C12 aryl group,
- Z represents an ether bond, a carbonyl group, an ester bond or a single bond,
- a is an integer of 1-3, and
- Y represents an ether bond or an ester group),
- (in formula (2),
- R4-R7 each independently represent hydrogen, fluorine, chlorine, bromine, iodine, or an optionally substituted C1-C20 alkyl group, C6-C12 aryl group, C2-C12 alkenyl group, C1-C5 alkoxy group or C7-C17 aralkyl group, and
- X is —O—, —S—, —SO—, —SO2—, —CO— or a divalent group represented by any of general formulae (4)-(6) or (8) below)
- in general formulae (4)-(6) and (8),
- R18 and R19 each independently represent hydrogen, a halogen, an optionally substituted C1-C20 alkyl group, an optionally substituted C1-C5 alkoxy group, an optionally substituted C6-C12 aryl group, an optionally substituted C7-C17 aralkyl group or an optionally substituted C2-C15 alkenyl group, or
- R18 and R19 bind to each other to form a C3-C20 carbocyclic ring or a C1-C20 heterocyclic ring,
- R20 is an optionally substituted C1-C9 alkylene group,
- c represents an integer of 0-20, and
- d represents an integer of 1-500);
- wherein the terminal structure represented by structural formula (1) is contained in an amount of 0.5 mol % to 8 mol % relative to the amount of the structural unit (2).
A resin solution comprising a polycarbonate resin composition and a nonhalogenated organic solvent, wherein at least a part of the polycarbonate resin composition is crosslinked, wherein the polycarbonate resin composition comprising:
- 100 parts by mass of a terminal-modified polycarbonate resin (A) having a terminal structure represented by structural formula (1) below and a structural unit (2) below;
- and
- not less than 0.1 parts by mass of a polyisocyanate compound,
- (in formula (1),
- R1 represents an optionally substituted C1-C20 alkylene group or C2-C20 alkenylene group,
- R2 and R3 each independently represent hydrogen, a C1-C20 alkyl group, a C1-C10 alkoxy group or a C6-C12 aryl group,
- Z represents an ether bond, a carbonyl group, an ester bond or a single bond,
- a is an integer of 1-3, and
- Y represents an ether bond or an ester group),
- (in formula (2),
- R4-R7 each independently represent hydrogen, fluorine, chlorine, bromine, iodine, or an optionally substituted C1-C20 alkyl group, C6-C12 aryl group, C2-C12 alkenyl group, C1-C5 alkoxy group or C7-C17 aralkyl group, and
- X is —O—, —S—, —SO—, —SO2—, —CO— or a divalent group represented by any of general formulae (4)-(6), or (8) below)
- in general formulae (4)-(6) and (8),
- R18 and R19 each independently represent hydrogen, a halogen, an optionally substituted C1-C20 alkyl group, an optionally substituted C1-C5 alkoxy group, an optionally substituted C6-C12 aryl group, an optionally substituted C7-C17 aralkyl group or an optionally substituted C2-C15 alkenyl group, or
- R18 and R19 bind to each other to form a C3-C20 carbocyclic ring or a C1-C20 heterocyclic ring,
- R20 is an optionally substituted C1-C9 alkylene group,
- c represents an integer of 0-20, and
- d represents an integer of 1-500);
- wherein the terminal structure represented by structural formula (1) is contained in an amount of 0.5 mol % to 8 mol % relative to the amount of the structural unit (2).
Dependencies are inferred from the claim text.