Curable resin composition
AssigneeCanon Kabushiki Kaisha
InventorsKyohei Wada, Chiaki Nishiura, Ryo Ogawa
Life of this patent
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Abstract
A curable resin composition includes (A) a specific curable resin and (C) a curing agent, and further includes (BI) 0.1 parts by mass or more and 20 parts by mass or less of a polyhydric alcohol having 2 to 5 hydroxyl groups, based on based on 100 parts by mass of the curable resin (A); (BII) a cyclic compound having 3 to 6 reactive groups and a reactive group equivalent of 100 g/eq or more and 300 g/eq or less; or (BIII) a specific oxetane compound in a mass ratio of the curable resin (A) to the oxetane compound (BIII) being 5:5 to 9:1.
Claims21
A method of manufacturing a three-dimensional shaped article, comprising the steps of:
- preparing a curable resin composition that comprises a first component, a second component and a curing agent;
- forming a first layer of the curable resin composition;
- photocuring the first layer of the curable resin composition based on a first slice data to shape a first part of the shaped article;
- forming a second layer of the curable resin composition;
- photocuring the second layer of the curable resin composition based on a second slice data to shape a second part of the shaped article;
- and
- removing a part of the curable resin composition from a surface of a cured product including the first part and the second part, wherein
- the second component is an oxetane compound, and
- the first component is represented by formula (1)
- where X1 and X2 are independently a divalent linking group containing an aromatic ring,
- L1, L2, L3 and L4 are independently a divalent linking group containing one or more bonds selected from the group consisting of —O—, —C—O—, —S—, —CS—, an ester bond, a urethane bond, an ether bond, a thiourethane bond and a thioether bond,
- Y1 and Y2 are independently an epoxy group, a cycloalkene oxide group or an oxetanyl group,
- n is an average value of repeating structural units and is a real number of 0.1 to 10, and
- X3 is represented by formula (1-VIII)
- where m is an integer selected so that the alkylene group has 4 to 18 carbon atoms,
- R1 and R2 are hydrogen or a methyl group, and
- * denotes a bond to L1 or L2.
Dependencies are inferred from the claim text.