Heterocyclic red azo colorants for seed treatment applications
AssigneeMilliken & Company
InventorsWesley A. Freund, Innus Mohammad
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Abstract
This invention relates to heterocyclic red azo colorants for seed treatment applications. The red azo colorants contain a heterocycle that includes one nitrogen atom and one sulfur atom and are free from electron-withdrawing groups on the heterocycle. Seeds for use in horticultural/agriculture applications that are coated with the heterocyclic azo colorants provide anti-counterfeiting properties to the coated seeds. A color change phenomenon is observed when the coated seeds are exposed to an acidic material, such as vinegar, and provides evidence of the authenticity of the coated seeds. The invention also relates to agricultural formulations containing the heterocyclic red azo colorants that can be used as an anti-counterfeit agents.
Claims15
A method for determining the authenticity of a seed or an agricultural formulation comprising the following steps:
- (a) Providing a seed or an agricultural formulation that contains a red azo colorant represented by the following formula:
- wherein R1 is a heterocyclic group comprising at least one 5-membered ring incorporating one N and one S atom, and wherein the heterocyclic group is free from electron-withdrawing groups;
- R2 and R3 are independently selected from the group consisting of H, alkyl, and poly(oxyalkylene) moieties, wherein at least one of R2 and R3 is a poly(oxyalkylene) moiety;
- and
- R4 is independently selected from the group consisting of H, alkyl, substituted alkyl, substituted nitrogen, hydroxyl, halogens and ethers;
- (b) Adding an acidic material to the seed or agricultural formulation of step “a;” and
- (c) Visually observing the occurrence of a color change from red to violet with the addition of the acidic material.
Dependencies are inferred from the claim text.