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US 12,281,200 B2Granted
Fluoropolyether group-containing compound
AssigneeDaikin Industries, Ltd.
InventorsHideyuki Ikeuchi, Masato Naitou, Motoshi Matsui, Takashi Nomura
Life of this patent
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Abstract
A fluoropolyether group-containing compound of formula (1a) or formula (1b): wherein RF1, RF2, R1 and R2 are as defined herein.
Claims10
A method for producing a fluoropolyether group-containing compound comprising:
- a compound of the following formula (1a) or (1b):
- and a compound of the following formula (2c):
- H—C≡C—X2-A2R213 (2c)
- are added with an organic lithium to obtain the fluoropolyether group-containing compound of formula (2a) or formula (2b):
- wherein
- RF1 is each independently at each occurrence Rf1—RF—Oq—;
- RF2 is —Rf2p—RF—Oq—;
- Rf1 is each independently at each occurrence a C1-16 alkyl group optionally substituted with one or more fluorine atoms;
- Rf2 is a C1-6 alkylene group optionally substituted with one or more fluorine atoms;
- RF is each independently at each occurrence a divalent fluoropolyether group;
- p is 0 or 1;
- q is each independently at each occurrence 0 or 1;
- and
- R1 and R2, each independently at each occurrence, are an alkyl group or an alkoxy group having 1 to 10 carbon atoms, or together form a group having a ring structure which is a 5 to 10-membered heterocyclic ring, or together form a group having a ring structure which is a condensed ring containing a 5 to 10-membered heterocyclic ring, wherein the alkyl group, the alkoxy group and the group having the ring structure may be substituted;
- X2 is a divalent organic group;
- A2 is each independently at each occurrence C or Si;
- and
- R21 is each independently a hydrocarbon group having at least one carbon-carbon double bond.
15 more elements
A method for producing a fluoropolyether group-containing compound comprising reducing a compound of the following formula (1a) or (1b) in the presence of an alkyllithium to obtain the fluoropolyether group-containing compound of formula (4a) or formula (4b):
- wherein
- RF1 is each independently at each occurrence Rf1—RF—Oq—;
- RF2 is —Rf2p—RF—Oq—;
- Rf1 is each independently at each occurrence a C1-16 alkyl group optionally substituted with one or more fluorine atoms;
- Rf2 is a C1-6 alkylene group optionally substituted with one or more fluorine atoms;
- RF is each independently at each occurrence a divalent fluoropolyether group;
- p is 0 or 1;
- q is each independently at each occurrence 0 or 1.
5 more elements
Dependencies are inferred from the claim text.