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US 12,275,004 B2Granted
Catalyst for synthesizing dimethylether or methylacetate from synthetic gas, method for preparing the same, and method for preparing dimethylether or methylacetate using the same
AssigneesHyundai Motor Company, Kia Corporation, Research & Business Foundation Sungkyunkwan University
InventorsChae Hwan Hong, Jin Woo Choung, Young Gul Hur, Jong Wook Bae, Hyun Seung Jung
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Abstract
The present disclosure provides a method of preparing a catalyst for synthesizing dimethyl ether or methylacetate from synthetic gas that includes preparing a nanosheet ferrierite zeolite (FER), and co-precipitating the nanosheet ferrierite zeolite and a precursor of a Cu—Zn—Al-based oxide (CZA) to obtain a hybrid CZA/FER catalyst.
Claims3
A hybrid CZA/FER catalyst comprising:
- a nanosheet ferrierite zeolite;
- and
- a Cu—Zn—Al-based oxide supported on the nanosheet ferrierite zeolite;
- wherein the nanosheet ferrierite zeolite has a shape in which one or more sheets having a thickness of about 5 nm to about 10 nm and a width of about 100 nm to about 150 nm are stacked;
- and
- wherein an amount of weak acid sites in the nanosheet ferrierite measured through NH3-TPD analysis is about 0.562 mmol/gcat to about 0.736 mmol/gcat;
- an amount of medium acid sites in the nanosheet ferrierite measured through NH3-TPD analysis is about 0.118 mmol/gcat to about 0.243 mmol/gcat;
- an amount of strong acid sites in the nanosheet ferrierite measured through NH3-TPD analysis is about 0.423 mmol/gcat to about 0.552 mmol/gcat;
- an amount of Brönsted acid sites in the nanosheet ferrierite measured through Py-IR analysis is about 0.126 mmol/gcat to about 0.266 mmol/gcat;
- an amount of Lewis acid sites in the nanosheet ferrierite measured through Py-IR analysis is about 3.130×102 mmol/gcat to about 3.962×102 mmol/gcat;
- or
- an amount of Brönsted acid sites in 8 membered-rings of the nanosheet ferrierite combined NH3-TPD and Py-IR analysis results is about 0.250 mmol/gcat to about 0.297 mmol/gcat.
9 more elements
Dependencies are inferred from the claim text.