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US 12,274,988 B2Granted
Dendrimeric carbon dot-polyamide membranes
AssigneesSaudi Arabian Oil Company, King Fahd University of Petroleum and Minerals
InventorsTawfik A. Saleh, Fahd Ibrahim AlGhunaimi, Norah Aljuryyed, Hind S. Aldossary
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Abstract
A dendrimeric carbon dot-polyamide membrane, a method for making the dendrimeric carbon dot-polyamide membrane, and a method for producing purified water are provided. An exemplary carbon dot-polyamide membrane includes polyamidoamine dendrimeric carbon dots and a polyamide membrane. The polyamidoamine dendrimeric dots are dispersed throughout the polyamide membrane.
Claims19
A method of making a dendrimeric carbon dot-polyamide membrane, comprising:
- forming dendrimeric carbon dots;
- preparing a porous membrane substrate to yield a prepared porous membrane substrate;
- dispersing the dendrimeric carbon dots in a solvent containing m-phenylenediamine to yield a mixture;
- immersing the prepared porous membrane substrate into the mixture;
- coating the mixture in a presence of trimesoyl chloride to yield a thin-film-composite membrane precursor;
- and
- heating the thin-film-composite membrane precursor to yield the dendrimeric carbon dot-polyamide membrane;
- wherein the dendrimeric carbon dots comprise polyamidoamine dendrimeric carbon dots, and forming the polyamidoamine dendrimeric carbon dots comprises:
- obtaining carbon dots;
- combining the carbon dots with an oxidant to yield oxidized carbon dots;
- combining the oxidized carbon dots with a reaction mixture comprising glycine and a catalyst under an atmosphere of nitrogen to yield esterified carbon dots;
- combining the esterified carbon dots with methyl methacrylate to yield half generation dendrimeric carbon dots;
- combining the half generation dendrimeric carbon dots with ethylenediamine to form full generation dendrimeric carbon dots;
- and
- combining the full generation dendrimeric carbon dots with methyl methacrylate and ethylenediamine a number of times to form polyamidoamine dendrimeric carbon dots.
12 more elements
Dependencies are inferred from the claim text.