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US 12,263,470 B2Granted
Method of improving selective hydrogenation of unsaturated hydrocarbon in aromatic fraction through catalyst pretreatment
AssigneesSK Innovation Co., Ltd., SK Geo Centric Co., Ltd.
InventorsSang Il Lee, Ji Hoon Lee
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Abstract
Disclosed is a method for providing improved hydrogenation activity by pretreating a catalyst in a three-step manner before selective hydrogenation of unsaturated hydrocarbons in an aromatic fraction in the presence of an oxide-type bimetallic (particularly nickel-molybdenum) supported catalyst.
Claims20
A method for removing unsaturated hydrocarbons from aromatic hydrocarbons, which comprises the steps of:
- providing an aromatic hydrocarbon-containing feedstock having a bromine index of at least 30;
- and
- forming an aromatic hydrocarbon-containing product having a decreased bromine index compared to the feedstock by hydrogenating the aromatic hydrocarbon-containing feedstock in presence of a selective hydrogenation catalyst prepared using a method comprising the steps of:
- a) providing a calcined catalyst containing nickel and molybdenum;
- b) sulfiding the calcined catalyst containing nickel and molybdenum to give a sulfided catalyst containing nickel and molybdenum;
- c) carrying out an oxidation treatment of the sulfided catalyst containing nickel and molybdenum at a temperature exceeding 250° C. to give an oxidized catalyst containing nickel and molybdenum;
- and
- d) carrying out a reduction treatment of the oxidized catalyst containing nickel and molybdenum to give a reduced catalyst containing nickel and molybdenum.
5 more elements
Dependencies are inferred from the claim text.