Vinyl acetate-silicone copolymer resin and method for producing same
AssigneeNissin Chemical Industry Co., Ltd.
InventorsKoki Uchida, Kentaro Watanabe
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Abstract
The present invention provides a vinyl acetate-silicone copolymer resin obtained by graft polymerization of vinyl acetate (B) onto an organopolysiloxane (A) represented by a specific general formula, wherein a weight ratio of the organopolysiloxane (A) to the vinyl acetate (B) is (A):(B)=10:90 to 95:5, a method for producing the same, and a vinyl acetate-silicone copolymer resin composition. The vinyl acetate-silicone copolymer resin of the present invention has slidability, substrate adhesiveness, and organic solvent solubility, and is suitably used for coating agents for various substrates, adhesive agents, exterior and interior paints for structures and building materials and the like, and cosmetics and the like.
Claims8
A vinyl acetate-silicone copolymer resin obtained by graft polymerization of vinyl acetate (B) onto an organopolysiloxane (A) of the following general formula (1), wherein
- a weight ratio of the organopolysiloxane (A) to the vinyl acetate (B) is (A):(B)=30:70 to 70:30,
- wherein R1 is the same or different substituted or unsubstituted monovalent hydrocarbon group of 1 to 20 carbon atoms selected from the group consisting of alkyl groups, cycloalkyl groups, aryl groups, alkenylaryl groups, alkenylaralkyl groups, a substituted one in which a part or all hydrogen atoms of the above groups are substituted with a halogen atom, a carboxyl group, an alkoxy group, an alkenyloxy group, an amino group, and an alkyl-, alkoxy- or (meth)acryloxy-substituted amino group, R2 is a mercapto, acryloxy or methacryloxy group-substituted alkyl group having 1 to 6 carbon atoms, or a vinyl group, X is the same or different substituted or unsubstituted monovalent hydrocarbon group of 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, or a hydroxyl group, Y is the same or different group of X or —[O—Si(X)2]d—X, at least one of Y being a hydroxyl group or —[O—Si(X)2]d-X, at least two of X and Y being hydroxyl groups, Z is an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, or a hydroxyl group, a is a positive number of 0 to 1,000, b is a positive number of 100 to 10,000, c is a positive number of 1 to 10, and d is a positive number of 1 to 1,000, and wherein the vinyl acetate-silicone copolymer resin is an emulsion having a viscosity (25° C.) of 1 to 500 mPa·s.
A method for producing a vinyl acetate-silicone copolymer resin,
- the method comprising subjecting an organopolysiloxane (A) of the following general formula (1) and vinyl acetate (B) to emulsion polymerization at a weight ratio of (A):(B)=30:70 to 70:30 to obtain a vinyl acetate-silicone copolymer resin emulsion:
- wherein R1 is the same or different substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms selected from the group consisting of alkyl groups, cycloalkyl groups, aryl groups, alkenylaryl groups, alkenylaralkyl groups, a substituted one in which a part or all hydrogen atoms of the above groups are substituted with a halogen atom, an acryloxy group, a methacryloxy group, a carboxyl group, an alkoxy group, an alkenyloxy group, an amino group, and an alkyl-, alkoxy- or (meth)acryloxy-substituted amino group,
- R2 is a mercapto, acryloxy or methacryloxy group-substituted alkyl group having 1 to 6 carbon atoms, or a vinyl group,
- X is the same or different substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, or a hydroxyl group,
- Y is the same or different group of X or —[O—Si(X)2]d—X, at least two of X and Y being hydroxyl groups, Z is an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, or a hydroxyl group, a is a positive number of 0 to 1,000, b is a positive number of 100 to 10,000, c is a positive number of 1 to 10, and d is a positive number of 1 to 1,000.
Dependencies are inferred from the claim text.