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US 12,252,455 B2Granted
Process for the continuous preparation of heavy alkyl acrylates
AssigneeArkema France
InventorsClement Bellini, Sandra Maget, Patrice Defer
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Abstract
The present invention relates to a process for the continuous synthesis of heavy alkyl acrylates by a transesterification reaction using hydrozincite as a heterogeneous catalyst.
Claims13
A process for the continuous synthesis of (meth)acrylic esters of formula (I):
- in which R is a hydrogen atom or a methyl group, and R1 is a linear or branched alkyl radical, or a cycloaliphatic, aryl, alkylaryl or arylalkyl radical, including from 4 to 40 carbon atoms, or a linear or branched alkyl radical containing at least one heteroatom and from 3 to 40 carbon atoms, comprising the step of reacting an alkyl (meth)acrylate of formula (II):
- in which R has the abovementioned meaning and R2 is a linear or branched alkyl group containing from 1 to 3 carbon atoms, with an alcohol of formula (III):
- R1—OH (III)
- in the presence of at least one polymerization inhibitor and hydrozincite as heterogeneous catalyst,
- wherein the catalyst content is between 0.01 mol_% and 0.5 mol % relative to the alcohol.
2 more elements
Dependencies are inferred from the claim text.