Compound, tautomer of compound or salt of compound or tautomer, method for producing same, coloring composition, dyeing method, and dyed article
AssigneeFUJIFILM Corporation
InventorsYoshihiro Jimbo, Yasuhiro Ishiwata, Motoki Ueda, Yoshihiko Fujie
Life of this patent
Estimating the term…
Abstract
Provided are a compound represented by Formula 1, a tautomer of the compound or a salt of the compound or the tautomer, a coloring composition and a dyed article containing the compound represented by Formula 1, the tautomer of the compound, or the salt of the compound or the tautomer, and a dyeing method using the compound represented by Formula 1, the tautomer of the compound, or the salt of the compound or the tautomer. In Formula 1, X, R, Ar, n, and m1 are as defined in the specification.
Claims13
A compound represented by Formula 1, a tautomer of the compound, or a salt of the compound or the tautomer,
- wherein, in Formula 1, X— represents R1O—, R2aR2bN—, or R3S—, R1, R2a, and R2b each independently represent a hydrogen atom or an alkyl group, R3 represents an alkyl group, in a case where X— is R2aR2bN—, R2a and R2b may be the same or different from each other and R2a and R2b may be bonded to each other to form a nitrogen-containing hetero ring, R's each independently represent a substituent, n represents 0, 1, 2, or 3, in a case where n represents 2 or 3, R′s may be the same or different from each other, Ar represents an aromatic hydrocarbon group or a heterocyclic group, m1 represents 2 or 3, and in a case where ml represents 2 or 3, Ar's may be the same or different from each other, provided that at least one of Ar's is a heterocyclic group, and
- wherein the at least one of Ar's is a group represented by any of the group consisting of Formulae (A-1) to (A-27) and (A-28):
- in Formulae (A-1) to (A-25), (A-27) and (A-28), * represents a position bonded to an azo group in Formula 1, R21 to R27, R29, R31, and R33 to R53 each independently represent a halogen atom, an alkyl group, an aryl group, a heterocyclic group, a cyano group, a hydroxy group, a nitro group, an alkoxy group, an aryloxy group, an amino group, an acylamino group, an aminocarbonylamino group, an alkoxycarbonylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, an alkylthio group, an arylthio group, a heterocyclicthio group, a sulfamoyl group, an alkylsulfonyl group, an arylsulfonyl group, an acyl group, an alkoxycarbonyl group, or a carbamoyl group, R28 R30, and R32 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a heterocyclic group, a cyano group, a hydroxy group, a nitro group, an alkoxy group, an aryloxy group, an amino group, an acylamino group, an aminocarbonylamino group, an alkoxycarbonylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, an alkylthio group, an arylthio group, a heterocyclicthio group, a sulfamoyl group, an alkylsulfonyl group, an arylsulfonyl group, an acyl group, an alkoxycarbonyl group, or a carbamoyl group, adjacent groups among R21 to R53 may be bonded to each other to form a saturated or unsaturated 5- or 6-membered ring structure, a, p, q, r, and s represent an integer of 0 to 4, b and c represent an integer of 0 to 6, d, e, f, g, t, and u represent an integer of 0 to 3, h, i, j, k, l, and o represent an integer of 0 to 2, w represents an integer of 0 to 5, m represents 0 or 1, and two or more groups represented by R21 to R53 in a same molecule may be the same or different from each other.
A method for producing a compound represented by Formula 1, a tautomer of the compound, or a salt of the compound or the tautomer,
- wherein, in Formula 1, X— represents R1O—, R2aR2bN—, or R3S—, R1, R2a, and R2b each independently represent a hydrogen atom or an alkyl group, R3 represents an alkyl group, in a case where X— is R2aR2bN—, R2a and R2b may be the same or different from each other and R2a and R2b may be bonded to each other to form a nitrogen-containing hetero ring, R's each independently represent a substituent, n represents 0, 1, 2, or 3, in a case where n represents 2 or 3, R's may be the same or different from each other, Ar represents an aromatic hydrocarbon group or a heterocyclic group, ml represents 2 or 3, and in a case where ml represents 2 or 3, Ar's may be the same or different from each other, provided that at least one of Ar's is a heterocyclic group,
- the method comprising:
- a step of reacting a diazonium salt represented by Formula 5 with a compound represented by Formula 13 to obtain a compound represented by Formula 14;
- and
- a step of reacting the obtained compound represented by Formula 14 with a diazonium salt represented by Formula 8 to obtain a compound represented by Formula 15,
- in Formula 5, Formula 8, and Formulae 13 to 15, Ar1 and Ar2 each independently represent an aromatic hydrocarbon group or a heterocyclic group, R2a and R2b each independently represent a hydrogen atom or an alkyl group, R2a and R2b may be the same or different from each other, R2a and R2b may be bonded to each other to form a nitrogen-containing hetero ring, R represents a substituent, n1 represents 0, 1, or 2, and in a case where n1 represents 2, R's may be the same or different from each other, provided that Ar1 and Ar2 are not simultaneously aromatic hydrocarbon groups.
Dependencies are inferred from the claim text.