Chiral-substituted poly-N-vinylpyrrolidinones and complexes with bimetallic nanoclusters and uses thereof in asymmetric oxidation reactions
AssigneeKansas State University Research
InventorDuy H. Hua
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Abstract
Chiral polyvinylpyrrolidinone (CSPVP), complexes of CSPVP with a core species, such as a bimetallic nanocluster catalyst, and enantioselective oxidation reactions utilizing such complexes are disclosed. The catalytic complexes have exhibited the ability to achieve reaction products have a very high degree of optical purifies. These reaction products can be used as reagents in the synthesis of complex organic molecules, such as bioactive products, and C—H bond oxidation of complex molecules including various drugs and natural products.
Claims25
A chiral substituted polyvinylpyrrolidinone compound having the formula
- wherein each R is individually selected from the group consisting of OH and C1-C30 aliphatic and aromatic functional groups, and n is greater than 50.
Dependencies are inferred from the claim text.