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US 12,234,577 B2Granted
Process for the manufacture of a precursor yarn
AssigneeStora Enso OYJ
InventorsNiklas Garoff, Robert Protz, Jens Erdmann, Johannes Ganster, Andre Lehmann
Life of this patent
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Abstract
The present invention relates to a method for manufacturing precursor yarn comprising lignin, which may be further processed into intermediate carbon fibers and finally also carbon fibers. It also relates to carbon fibers and uses of said fibers. Said method involves applying a water-free spin finish.
Claims27
A method for manufacturing a precursor yarn comprising lignin, comprising:
- a) providing cellulose and/or a cellulose derivative,
- b) providing lignin and/or a lignin derivative,
- c) dissolution of the cellulose and/or the cellulose derivative and the lignin and/or the lignin derivative in a solvent followed by subsequent mixing thus providing a dope consisting essentially of the cellulose and/or the cellulose derivative and the lignin and/or the lignin derivative and the solvent,
- d) performing a spinning of the dope to a precursor material,
- e) applying a water-free spin finish on said precursor material, and
- f) drying of said precursor material, thus providing a precursor yarn comprising lignin,
- wherein the water-free spin finish in step e) consists essentially of at least one organic solvent with a boiling point lower than that of water, and one or more anti-static agents or one or more anti-friction agents or both, wherein the at least one organic solvent consists essentially of one or more aprotic polar solvent selected from ketoalkyl or ketoalkoxy compounds and has the structure shown below,
- and wherein
- R1=H, CH3, O-(CH2)n-CH3;
- n=0-3,
- R2=H, CH3, O-(CH2)n-CH3;
- n=0-3, and
- optionally one or more protic polar solvent, and wherein the water-free spin finish is applied on said precursor material before drying of said precursor material.
10 more elements
A method for manufacturing a precursor yarn comprising lignin, comprising:
- a) providing cellulose and/or a cellulose derivative,
- b) providing lignin and/or a lignin derivative,
- c) dissolution of the cellulose and/or the cellulose derivative and the lignin and/or the lignin derivative in a solvent followed by subsequent mixing thus providing a dope consisting essentially of the cellulose and/or the cellulose derivative and the lignin and/or the lignin derivative and the solvent,
- d) performing a spinning of the dope to a precursor material,
- e) applying a water-free spin finish on said precursor material,
- f) drying of said precursor material, thus providing a precursor yarn comprising lignin, and
- g) performing a stabilization on the precursor yarn to produce a stabilized carbon fibre,
- wherein the water-free spin finish in step e) consists essentially of at least one organic solvent with a boiling point lower than that of water, and one or more anti-static agentsor one or more anti-friction agents or both, wherein the at least one organic solvent consists essentially of an aprotic polar solvent selected from ketoalkyl or ketoalkoxy compounds and has the structure shown below,
- and wherein
- R1=H, CH3, O-(CH2)n-CH3;
- n=0-3,
- R2=H, CH3, O-(CH2)n-CH3;
- n=0-3, and
- wherein the water-free spin finish is applied on said precursor material before drying of said precursor material.
11 more elements
Dependencies are inferred from the claim text.