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US 12,230,759 B2Granted
Electrolyte for lithium secondary battery and lithium secondary battery including the same
AssigneeSK On Co., Ltd.
InventorsIn Haeng Cho, Dong Gun Lee, Joo Hyun Lee, Sung Jin Kim
Life of this patent
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Abstract
An electrolyte for a lithium secondary battery according to exemplary embodiments of the present inventing includes an organic solvent, a lithium salt, a first additive represented by a predetermined chemical formula, and a second additive represented by a predetermined chemical formula. A protective film is formed by the additives to suppress an expansion of a lithium secondary battery and improve storage property at high temperature.
Claims14
An electrolyte for a lithium secondary battery, comprising:
- an organic solvent;
- a lithium salt;
- a first additive represented by Chemical Formula 1;
- and
- a second additive represented by Chemical Formula 2,
- wherein a weight ratio of the first additive and the second additive is from 1:0.25 to 1:3:
- wherein, in Chemical Formula 1, R1 is a saturated hydrocarbon backbone structure having 3 to 10 carbon atoms, and n is an integer of 1 to 3,
- wherein, in Chemical Formula 2, R11 to R13 are each independently hydrogen, or a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, and A is a substituent represented by Chemical Formula 3 or Chemical Formula 4,
- wherein, in Chemical Formulae 3 and 4, R14 and R15 are each independently a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted aryl group having 6 to 12 carbon atoms, or —OR16, and
- R16 is a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted aryl group having 6 to 12 carbon atoms, or an alkynyl group having 2 to 6 carbon atoms.
7 more elements
Dependencies are inferred from the claim text.