# US 12,225,745 B2 · Quantum-dot display substrate and method for preparing the same, and display device

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 12,225,745 B2
- Document ID: US12225745B2
- Status: Granted
- Kind: B2
- Application number: 17/280,118
- Filed: 2020-07-01
- Published: 2022-01-06
- Granted: 2025-02-11
- Earliest claimed: 2019-07-03
- Assignees: Boe Technology Group Co., Ltd.
- Applicants: Boe Technology Group Co., Ltd.
- Inventors: Boris Kristal
- Web page: https://patentgrep.com/patent/US12225745B2

## CPC

- H10K 59/35: comprising red-green-blue [RGB] subpixels
- H10K 50/115: comprising active inorganic nanostructures, e.g. luminescent quantum dots
- H10K 50/15: Hole transporting layers
- H10K 50/16: Electron transporting layers
- H10K 50/171: {Electron injection layers}
- H10K 85/761: {Biomolecules or bio-macromolecules, e.g. proteins, chlorophyl, lipids or enzymes}
- H10K 59/1201: {Manufacture or treatment}
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES

## Abstract

The present disclosure provides a quantum-dot display substrate, a method for preparing the same, and a display device. The quantum dot display substrate includes a first electrode, a second electrode, and a quantum-dot-emitting layer located between the first electrode and the second electrode, and the quantum-dot-emitting layer includes: a DNA single-stranded structure of a specific pattern, with quantum dots attached to the DNA single-stranded structure.

## Claims

### Claim 1

A quantum dot display substrate, comprising a first electrode, a second electrode, and a quantum-dot-emitting layer located between the first electrode and the second electrode, wherein the quantum-dot-emitting layer comprises: a DNA single-stranded structure of a specific pattern, with quantum dots attached to the DNA single-stranded structure,
wherein the DNA single-stranded structure of the specific pattern comprises:
long single-stranded DNA molecules having a length of greater than 30 nm and less than 1000 microns, with a plurality of quantum dots in different colors attached to different long single-stranded DNA molecules respectively; and
a staple DNA molecule, through which the long single-stranded DNA molecules are folded into the specific pattern,
wherein the DNA single-stranded structure of the specific pattern comprises a plurality of DNA tile structures, and each of the plurality of DNA tile structures comprises:
a plurality of first long single-stranded DNA molecules for forming a pattern scaffold of the specific pattern;
a plurality of second staple DNA molecules connected to the plurality of first long single-stranded DNA molecules, with quantum dots in a same color attached to the plurality of second staple DNA molecules;
a third staple DNA molecule connected to adjacent first long single-stranded DNA molecules; and
a fourth staple DNA molecule connected to the plurality of first long single-stranded DNA molecules and located at an edge of the plurality of DNA tile structures,
wherein each of the plurality of DNA tile structures is attached with quantum dots in a same color as one quantum dot unit,
each of the plurality of second staple DNA molecules is a short single-stranded DNA molecule having a length of 18 to 22 bases, which is an internal staple connected to a quantum dot; the third staple DNA molecule is a short single-stranded DNA molecule having a length of 18 to 22 bases, which is a bridge staple for assembling the plurality of first long single-stranded DNA molecules together; the fourth staple DNA molecule is an edge staple modified with nucleotide extension and truncation to form donor and acceptor DNA molecules.

### Claim 2 (depends on 1)

The quantum-dot display substrate of claim 1, wherein the staple DNA molecule is a short single-stranded DNA molecule having a length of 18 to 22 bases, and a base of the staple DNA molecule is complementary to a base of a specific region of the long single-stranded DNA molecule.

### Claim 3 (depends on 1)

The quantum-dot display substrate of claim 1, wherein adjacent DNA tile structures are connected through the fourth staple DNA molecule.

### Claim 4 (depends on 1)

The quantum-dot display substrate of claim 1, wherein the plurality of DNA tile structures has a size ranging from 80 nm to 200 nm.

### Claim 5 (depends on 3)

The quantum-dot display substrate of claim 3, wherein the fourth staple DNA molecule comprises an acceptor DNA molecule and a donor DNA molecule, with the acceptor DNA molecule and the donor DNA molecule capable of being connected in complementary pairing;
the quantum-dot-emitting layer comprises quantum dot units in different colors, and each of the quantum dot units in different colors comprises a first DNA tile structure and a second DNA tile structure, with an edge of the first DNA tile structure being the acceptor DNA molecule and an edge of the second DNA tile structure being the donor DNA molecule.

### Claim 6 (depends on 1)

The quantum-dot display substrate of claim 1, further comprising:
a hole injection material and a hole transport material that are located between the first electrode and the quantum-dot-emitting layer; and
an electron transport layer located between the second electrode and the quantum-dot-emitting layer.

### Claim 7 (depends on 1)

A display device, comprising the quantum-dot display substrate of claim 1.

### Claim 8

A method for preparing a quantum-dot display substrate, comprising forming a first electrode, a second electrode, and a quantum-dot-emitting layer located between the first electrode and the second electrode on a thin-film transistor array substrate, wherein the forming the quantum-dot-emitting layer comprises: forming a DNA single-stranded structure of a specific pattern, with quantum dots attached to the DNA single-stranded structure,
wherein the DNA single-stranded structure of the specific pattern comprises:
long single-stranded DNA molecules having a length of greater than 30 nm and less than 1000 microns, with a plurality of quantum dots in different colors attached to different long single-stranded DNA molecules respectively; and
a staple DNA molecule, through which the long single-stranded DNA molecules are folded into the specific pattern,
wherein the DNA single-stranded structure of the specific pattern comprises a plurality of DNA tile structures, and each of the plurality of DNA tile structures comprises:
a plurality of first long single-stranded DNA molecules for forming a pattern scaffold of the specific pattern;
a plurality of second staple DNA molecules connected to the plurality of first long single-stranded DNA molecules, with quantum dots in a same color attached to the plurality of second staple DNA molecules;
a third staple DNA molecule connected to adjacent first long single-stranded DNA molecules; and
a fourth staple DNA molecule connected to the plurality of first long single-stranded DNA molecules and located at an edge of the plurality of DNA tile structures,
wherein each of the plurality of DNA tile structures is attached with quantum dots in a same color as one quantum dot unit,
each of the plurality of second staple DNA molecules is a short single-stranded DNA molecule having a length of 18 to 22 bases, which is an internal staple connected to a quantum dot; the third staple DNA molecule is a short single-stranded DNA molecule having a length of 18 to 22 bases, which is a bridge staple for assembling the plurality of first long single-stranded DNA molecules together; the fourth staple DNA molecule is an edge staple modified with nucleotide extension and truncation to form donor and acceptor DNA molecules.

### Claim 9 (depends on 8)

The method of claim 8, wherein the forming the DNA single-stranded structure of the specific pattern comprises:
attaching quantum dots in different colors to different long single-stranded DNA molecules of micrometer scale respectively; and
folding the long single-stranded DNA molecules into the specific pattern by using a staple DNA molecule.

### Claim 10 (depends on 8)

The method of claim 8, wherein the forming the DNA single-stranded structure of the specific pattern comprises forming a plurality of DNA tile structures, and the forming the plurality of DNA tile structure comprises:
forming a pattern scaffold of the specific pattern by using a plurality of first long single-stranded DNA molecules;
attaching quantum dots in a same color to a plurality of second staple DNA molecules connected to the plurality of first long single-stranded DNA molecules, respectively; and
connecting adjacent first long single-stranded DNA molecules by using a third staple DNA molecule; and
forming a fourth staple DNA molecule connected to the plurality of first long single-stranded DNA molecules at an edge of the plurality of DNA tile structures.

### Claim 11 (depends on 10)

The method of claim 10, wherein the attaching quantum dots in the same color to the plurality of second staple DNA molecules comprises:
assembling a single-stranded DNA molecule modified with an oligohistidine segment and a polyethylene glycol functionalized quantum dot to attach the quantum dot to the single-stranded DNA molecule through an interaction between the oligohistidine segment and the polyethylene glycol.

### Claim 12 (depends on 10)

The method of claim 10, wherein the attaching quantum dots in the same color to the plurality of second staple DNA molecules comprises: coating the quantum dots with octylamine modified polyacrylic acid, conjugating the quantum dots coated with polyacrylic acid onto a primer, and attaching the quantum dots onto the DNA molecules through polymerase chain reaction.

### Claim 13 (depends on 8)

The method of claim 8, wherein the forming the DNA single-stranded structure of the specific pattern comprises: attaching a blue quantum dot, a red quantum dot, and a green quantum dot onto long single-stranded DNA molecules to form a DNA-quantum dot bioconjugate capable of emitting blue light, a DNA-quantum dot bioconjugate capable of emitting red light, and a DNA-quantum dot bioconjugate capable of emitting green light, respectively; and then folding these DNA-quantum dot bioconjugates into a desired pattern on the substrate by using a staple DNA molecule to complete a patterning of the quantum-dot-emitting layer, wherein the staple DNA molecule is a short single-stranded DNA molecule having a length of 18 to 22 bases.

### Claim 14 (depends on 8)

The method of claim 8, wherein after the forming the first electrode and before the forming the quantum-dot-emitting layer, the method further comprises:
forming a hole injection material and a hole transport material sequentially; and
after the forming the quantum-dot-emitting layer and before the forming the second electrode, the method further comprises:
forming an electron transport layer.

### Claim 15 (depends on 10)

The method of claim 10, wherein each of the plurality of second staple DNA molecules is complementary to a specific region of each of the plurality of first long single-stranded DNA molecules to form a double-stranded DNA molecule, with quantum dots in a same color attached onto each of the plurality of second staple DNA molecules.

### Claim 16 (depends on 10)

The method of claim 10, wherein each of the plurality of DNA tile structures is attached with quantum dots in a same color as one quantum dot unit.

### Claim 17 (depends on 10)

The method of claim 10, wherein edge staples of the plurality of DNA tile structures are extended and truncated to form the specific pattern, so that adjacent DNA tile structures are gathered together in a specific order.