# US 12,224,463 B2 · Installation and method for supplying a fuel cell with hydrogen

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 12,224,463 B2
- Document ID: US12224463B2
- Status: Granted
- Kind: B2
- Application number: 18/413,932
- Filed: 2024-01-16
- Published: 2024-05-09
- Granted: 2025-02-11
- Earliest claimed: 2020-03-25
- Assignees: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
- Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
- Inventors: Laurent Allidieres
- Web page: https://patentgrep.com/patent/US12224463B2

## CPC

- H01M 8/04089: of gaseous reactants
- H01M 8/04201: {Reactant storage and supply, e.g. means for feeding, pipes}
- F17C 13/025: {having the pressure as the parameter}
- H01M 8/04007: related to heat exchange
- H01M 8/04014: Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
- H01M 8/04208: {Cartridges, cryogenic media or cryogenic reservoirs}
- H01M 8/04753: {of fuel cell reactants}
- F17C 2205/0323: Valves
- F17C 2227/0302: by heating
- Y02E 60/32: Hydrogen storage
- Y02E 60/50: Fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- F17C: VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES (storing fluids in natural or artificial cavities or chambers in the earth B65G5/00; construction or assembling of bulk storage containers employing civil-engineering techniques E04H7/00; variable-capacity gas-holders F17B; liquefaction or refrigeration machines, plants, or systems F25)
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

An installation for supplying a fuel cell with hydrogen comprising a fuel cell, a liquefied hydrogen storage facility and a supply circuit that includes at least one upstream end connected to the storage facility and one downstream end connected to a fuel inlet of the fuel cell, the supply circuit including at least one system for heating hydrogen by heat exchange with a heat source and a set of control valves, the liquefied hydrogen storage facility being configured to keep the liquefied hydrogen in equilibrium with a gaseous phase at a determined nominal storage pressure of between 1.5 and 4.5 bar, the supply circuit including a buffer tank for pressurized gaseous hydrogen which is configured to store the hydrogen withdrawn from the storage facility and heated by the heating system, the set of valves being configured to accumulate pressurized gas in the buffer tank at a determined storage pressure of between 4 and 100 bar, for example between 6 and 8 bar.

## Claims

### Claim 1

An installation for supplying a fuel cell with hydrogen, the installation comprising:
the fuel cell;
a liquefied hydrogen storage tank; and
a supply circuit comprising at least one upstream end connected to the liquefied storage tank and one downstream end connected to a fuel inlet of the fuel cell, the supply circuit comprising: a set of control valves and a hydrogen heating system configured to heat hydrogen by heat exchange with a heat source, wherein the hydrogen heating system comprises a first heating heat exchanger, wherein the liquefied hydrogen storage tank is configured to keep the liquefied hydrogen in equilibrium with a gaseous phase at a determined nominal storage pressure of between 1.5 and 4.5 bar,
wherein the supply circuit further comprises a liquid withdrawal pipe and a buffer tank for pressurized gaseous hydrogen that is configured to store the hydrogen withdrawn from the liquefied hydrogen storage tank and heated by the hydrogen heating system,
wherein the set of control valves is configured to accumulate pressurized gas in the buffer tank at a determined storage pressure of between 4 and 100 bar,
wherein the liquid withdrawal pipe connects a lower portion of the liquefied hydrogen storage tank to the fuel inlet of the fuel cell, the liquid withdrawal pipe comprising, arranged in series, the first heating heat exchanger and a first pressure- and/or flow rate-regulating valve, said first pressure- and/or flow rate-regulating valve being configured to feed the fuel inlet of the fuel cell at a determined operating pressure of between 1 and 3 bar, wherein the fuel cell is fed with hydrogen by the liquefied hydrogen storage tank.

### Claim 2 (depends on 1)

The installation of claim 1, wherein the supply circuit further comprises a gas withdrawal pipe connecting an upper portion of the liquefied hydrogen storage tank to an inlet of the buffer tank.

### Claim 3 (depends on 2)

The installation of claim 2, wherein the hydrogen heating system further comprises a second heating heat exchanger that is in fluid communication with the gas withdrawal pipe and is configured to heat gaseous hydrogen, wherein the gas withdrawal pipe comprises, arranged in series, the second heating heat exchanger and a second pressure- and/or flow rate-regulating valve, said second pressure- and/or flow rate-regulating valve being configured to transfer gas at the storage pressure into the buffer tank.

### Claim 4 (depends on 3)

The installation of claim 3, wherein the second pressure- and/or flow rate-regulating valve is configured to automatically transfer gas from the liquefied hydrogen storage tank to the buffer tank only when the pressure in the liquefied hydrogen storage tank exceeds a determined pressure threshold.

### Claim 5 (depends on 2)

The installation of claim 2, wherein the supply circuit further comprises a set of isolation valves arranged at the inlet and the outlet of the buffer liquefied hydrogen storage tank, the hydrogen heating system comprising an exchange of heat between the fluid contained in the buffer tank and a heat source such as the atmosphere for vaporizing and increasing the pressure of the fluid in the buffer tank when the isolation valves are closed, the supply circuit furthermore comprising an element for limiting the pressure in said buffer tank such as a discharge valve which opens above a determined pressure threshold.

### Claim 6 (depends on 5)

The installation of claim 5, wherein the heat source is the atmosphere.

### Claim 7 (depends on 5)

The installation of claim 5, wherein the supply circuit further comprises a backup feed pipe connecting an outlet of the buffer tank to the fuel inlet of the fuel cell, the backup feed pipe comprising at least one fourth pressure- and/or flow rate-regulating valve configured to provide gas at a determined pressure to the fuel cell and, arranged in series, a valve shutter, the first heating heat exchanger, and a pressure-sensitive safety valve for discharging the gas to the outside of the supply circuit in the event of pressure above a safety threshold.

### Claim 8 (depends on 1)

The installation of claim 1, wherein the supply circuit further comprises a gas filling pipe having an upstream end connected to an outlet of the first heating heat exchanger and a downstream end connected to an inlet of the buffer tank, the gas filling pipe comprising a third pressure- and/or flow rate-regulating valve, said third pressure and/or flow rate regulator being configured to transfer gas at the storage pressure into the buffer tank.

### Claim 9 (depends on 1)

The installation of claim 1, wherein the supply circuit further comprises a liquid removal pipe having an upstream end connected to the lower portion of the liquefied hydrogen storage tank and a downstream end connected to an inlet of the buffer tank.

### Claim 10 (depends on 1)

The installation of claim 1, wherein the supply circuit further comprises a backup feed pipe connecting an outlet of the buffer tank to the fuel inlet of the fuel cell, the backup feed pipe comprising at least one fourth pressure- and/or flow rate-regulating valve configured to provide gas at a determined pressure to the fuel cell.

### Claim 11 (depends on 10)

The installation of claim 10, wherein the backup feed pipe is connected to the fuel inlet of the fuel cell via a connection to a portion of the liquid withdrawal pipe.

### Claim 12 (depends on 1)

The installation of claim 1, wherein the set of control valves is configured to accumulate pressurized gas in the buffer tank at a determined storage pressure of between 6 and 8 bar.

### Claim 13 (depends on 1)

The installation of claim 1, wherein the heating system can be selected from the group consisting of the first heating heat exchanger, a second heating heat exchanger, and combinations thereof.

### Claim 14 (depends on 1)

The installation of claim 1, wherein the installation is disposed onboard a vehicle.

### Claim 15 (depends on 14)

The installation of claim 14, wherein the vehicle is selected from the group consisting of a boat and a train.