# US 12,224,425 B2 · Magnetism alignment apparatus for negative electrodes and method for manufacturing negative electrode using same > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 12,224,425 B2 - Document ID: US12224425B2 - Status: Granted - Kind: B2 - Application number: 18/713,336 - Filed: 2023-09-13 - Published: 2024-11-28 - Granted: 2025-02-11 - Earliest claimed: 2022-09-15 - Assignees: LG Energy Solution, Ltd. - Applicants: LG Energy Solution, Ltd. - Inventors: Jong Su Yoon; Taek Soo Lee; Jin Ho Cho; Shin Wook Jeon; Young Gon Kim - Web page: https://patentgrep.com/patent/US12224425B2 ## CPC - H01M 4/0404: {by coating on electrode collectors} - H01M 4/1393: of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx - H01F 7/0247: {Orientating, locating, transporting arrangements} - H01M 4/0409: {by a doctor blade method, slip-casting or roller coating} - H01M 4/133: Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx - H01M 4/587: for inserting or intercalating light metals - H01M 10/0404: {Machines for assembling batteries} - H01F 7/0273: {Magnetic circuits with PM for magnetic field generation} - H01M 10/0525: Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries - H01M 2004/027: {Negative electrodes} - Y02E 60/10: Energy storage using batteries - H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY - H01F: MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES - Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION ## Abstract A magnetic alignment device for negative electrode and method for manufacturing negative electrode using the same. The magnetic alignment device can measure the loading amount of the negative electrode slurry applied on the negative electrode collector in real time and can easily control the intensity of the magnetic field by adjusting the separation distance of the magnet portion according to the measured negative electrode slurry loading amount, and has an advantage of uniformly high alignment degree of the crystal faces of the carbon-based negative electrode active material contained in prepared negative electrode active layer. ## Claims ### Claim 1 A magnetic alignment device for a negative electrode in which a negative electrode slurry including a carbon-based negative electrode active material is applied to a negative electrode sheet applied on a negative electrode collector to orient the carbon-based negative electrode active material by applying a magnetic force, the magnetic alignment device for negative electrode, comprising: a first magnet part and a second magnet part arranged at an upper portion and a lower portion of traveling electrode sheet, respectively; a loading amount measuring part arranged upstream of the first magnet part and the second magnet part relative to the travelling direction of the electrode sheet, and measuring the loading amount of the negative electrode slurry arranged on the electrode sheet; and a control part for adjusting a separation distance between the first magnet part and the second magnet part according to a loading amount of the negative electrode slurry measured by the loading amount measuring part. ### Claim 2 (depends on 1) The magnetic alignment device for negative electrode of claim 1, wherein the control part is equipped with a database in which an interval reference values of the first magnet part and the second magnet part according to the loading amount of the negative electrode slurry are stored, and the interval reference values corresponding to the loading amount of the negative electrode slurry measured by the loading amount measuring part are calculated to adjust the separation distance of the first magnet part and the second magnet part. ### Claim 3 (depends on 1) The magnetic alignment device for negative electrode of claim 1, wherein the first and second magnet parts each comprise a single permanent magnet arranged in the width direction of the driving negative electrode slurry; a support part to which the single permanent magnet is fixed; and distance adjustment means connected to the support part and inducing a lifting movement of the support part in a direction perpendicular to the traveling electrode sheet. ### Claim 4 (depends on 1) The magnetic alignment device for negative electrode of claim 1, wherein the separation distance between the first magnet part and the second magnet part is adjusted from 10 mm to 50 mm. ### Claim 5 (depends on 1) The magnetic alignment device for negative electrode of claim 1, wherein the first magnet part and the second magnet part comprise magnets having opposite poles. ### Claim 6 (depends on 1) The magnetic alignment device for negative electrode of claim 1, wherein the loading amount measuring part comprises at least one of a web gauge and an ultrasonic sensor. ### Claim 7 (depends on 6) The magnetic alignment device for negative electrode of claim 6, wherein the ultrasonic sensor comprises: an ultrasonic generating portion that injects ultrasonic waves onto a surface of the negative electrode slurry; an ultrasonic receiving part that scans the negative electrode slurry loaded with ultrasonic waves generated by the ultrasonic generating portion and receives the returned ultrasonic waves; and a data transmission part calculates the loading amount of the negative electrode slurry from the data obtained by the scan and transmits it to the control part. ### Claim 8 (depends on 1) The magnetic alignment device for negative electrode of claim 1, wherein the magnetic alignment device comprises a drying part for drying the negative electrode slurry in which the carbon-based negative electrode active material is aligned by the first magnet part and the second magnet part. ### Claim 9 (depends on 1) A method of manufacturing negative electrode, comprising: applying a negative electrode slurry comprising carbon-based negative electrode active material on a negative electrode collector; aligning the carbon-based negative electrode active material contained in the negative electrode slurry using a magnetic alignment device according to claim 1; and drying the negative electrode slurry in which the carbon-based negative electrode active material is aligned to form a negative electrode active layer, the step of aligning the carbon-based negative electrode active material provides a method of producing a controlled negative electrode by adjusting the spacing between the negative electrode slurry and the magnet part. ### Claim 10 (depends on 9) The method for manufacturing negative electrode of claim 9, wherein the negative electrode slurry is applied in a loading amount of 100 mg/25 cm′ to 500 mg/25 cm′. ### Claim 11 (depends on 9) The method for manufacturing negative electrode of claim 9, wherein the negative electrode active layer has an alignment degree of the carbon-based negative electrode active material of 0.1 to 5.0 shown in the following equation 1: O.I=I004/I110 Equation 1 in Equation 1, I004 represents the area of the peak representing the (0,0,4) crystal face in an X-ray diffraction spectroscopy measurement of the negative electrode active layer, and I110 represents the area of the peak representing the (1,1,0) crystal face in an X-ray diffraction spectroscopy measurement of the negative electrode active layer.