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US 12,221,458 B2Granted
Organic borate-based catalyst, method for preparing isobutene oligomer using the same and isobutene oligomer prepared thereby
AssigneeLG Chem, Ltd.
InventorsGyeong Shin Choi, Ji Hyun Choi, Won Hee Kim, Jin Lee, Dong Hyun Jo, Jeong Sik Kim
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Abstract
The present invention relates to an organic borate-based catalyst including a compound represented by the following Formula 1 and a hydroxyl group-containing compound, a method for preparing an isobutene oligomer using the same and an isobutene oligomer prepared thereby: wherein R0, R1 to R4, o, p, q and r are described therein.
Claims11
An organic borate-based catalyst comprising a compound represented by Formula 1 and a hydroxyl group-containing compound, wherein
- a silicon atom (Si) of the compound represented by Formula 1 and an oxygen atom (O) of the hydroxyl group-containing compound form a covalent bond:
- in Formula 1,
- each R0 is independently hydrogen, an alkyl group of 1 to 20 carbon atoms, an alkoxy group of 1 to 20 carbon atoms, an aryl group of 6 to 20 carbon atoms or an aryloxy group of 6 to 20 carbon atoms,
- R1 to R4 are each independently hydrogen, a halogen group or an alkyl group of 1 to 20 carbon atoms, and
- o, p, q and r are each independently an integer of 1 to 5,
- wherein the hydroxyl group-containing compound is a compound represented by Formula 2:
- in Formula 2,
- R5 to R7 are each independently hydrogen, a hydroxyl group, a hydroxyalkyl group of 1 to 20 carbon atoms, an alkyl group of 1 to 20 carbon atoms, an alkenyl group of 2 to 20 carbon atoms, an alkynyl group of 2 to 20 carbon atoms, a cycloalkyl group of 3 to 20 carbon atoms, an aryl group of 6 to 20 carbon atoms, a heteroaryl group of 5 to 20 carbon atoms, an alkoxy group of 1 to 20 carbon atoms, an aryloxy group of 6 to 20 carbon atoms, an alkylaryl group of 7 to 20 carbon atoms or an arylalkyl group of 7 to 20 carbon atoms, provided that at least two of R5 to R7 are not hydrogen, and one of R5 to R7 is an aryl group of 6 to 20 carbon atoms, a heteroaryl group of 5 to 20 carbon atoms, or an aryloxy group of 6 to 20 carbon atoms.
5 more elements
Dependencies are inferred from the claim text.