# US 12,218,311 B2 · Secondary battery, battery module, battery pack, and electrical device

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- Number: US 12,218,311 B2
- Document ID: US12218311B2
- Status: Granted
- Kind: B2
- Application number: 18/366,342
- Filed: 2023-08-07
- Published: 2023-11-23
- Granted: 2025-02-04
- Earliest claimed: 2021-10-29
- Assignees: Contemporary Amperex Technology (Hong Kong) Limited
- Applicants: Contemporary Amperex Technology (Hong Kong) Limited
- Inventors: Quanguo Li; Yonghuang Ye; Qian Liu; Jianfu He; Fajun Huang; Chenhui Lin
- Web page: https://patentgrep.com/patent/US12218311B2

## CPC

- H01M 10/0585: of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
- H01M 4/381: {Alkaline or alkaline earth metals elements (H01M4/40 takes precedence)}
- H01M 4/505: of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
- H01M 4/525: of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
- H01M 4/5825: {Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines}
- H01M 4/583: Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M 4/622: {being polymers}
- H01M 4/623: {fluorinated polymers}
- H01M 4/625: {Carbon or graphite}
- H01M 10/0525: Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
- H01M 2004/021: {Physical characteristics, e.g. porosity, surface area}
- H01M 2004/027: {Negative electrodes}
- H01M 2004/028: {Positive electrodes}
- H01M 2220/20: Batteries in motive systems, e.g. vehicle, ship, plane
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A secondary battery includes a positive electrode plate. that includes a positive current collector, a first positive active material layer distributed on one side of the positive current collector, and a second positive active material layer distributed on an other side of the positive current collector and a negative electrode plate that includes a negative current collector, a first negative active material layer distributed on one side of the negative current collector and opposite to the second positive active material layer, and a second negative active material layer distributed on an other side of the negative current collector. A resistance of the first positive active material layer is R1, a resistance of the second positive active material layer is R2, a resistance of the first negative active material layer is R3, a resistance of the second negative active material layer is R4.

## Claims

### Claim 1

A secondary battery, wherein the secondary battery comprises a positive electrode plate, a negative electrode plate, and a separator between the positive electrode plate and the negative electrode plate:
wherein the positive electrode plate comprises a positive current collector, a first positive active material layer distributed on one side of the positive current collector and a second positive active material layer distributed on another side of the positive current collector;
wherein the negative electrode plate comprises a negative current collector, a first negative active material layer distributed on one side of the negative current collector and opposite to the second positive active material layer and a second negative active material layer distributed on another side of the negative current collector;
a coating weight of a positive active material per unit area of the first positive active material layer is CW1 and a coating weight of the positive active material per unit area of the second positive active material layer is CW2;
wherein 6.5 mg/cm2≤CW1≤32.5 mg/cm2, 6.5 mg/cm2≤CW2≤32.5 mg/cm2 and 0.5≤CW1/CW2<1;
wherein the first negative active material layer and the second negative active material layer are different in composition and
wherein, a resistance of the first positive active material layer is R1, a resistance of the second positive active material layer is R2, a resistance of the first negative active material layer is R3, a resistance of the second negative active material layer is R4, and the resistances R1, R2, R3, and R4 are Ohmic resistances and satisfy the following relationships:
R2>R1; (1)
R3≥R4; (2)
0<(R1+R4)/(R2+R3)≤1; and (3)
R1/R2=A×R4/R3, wherein A is 0.8 to 1.2, (4)
wherein R1 is 0.1Ω to 20Ω, R2 is 0.15Ω to 22Ω, R3 is 0.7 mΩ to 40 mΩ, and
R4 is 0.5 mΩ to 35 mΩ.

### Claim 2 (depends on 1)

The secondary battery according to claim 1, wherein A is 0.95 to 1.05.

### Claim 3 (depends on 1)

The secondary battery according to claim 1, wherein R1 is 0.5Ω to 10Ω, R2 is 0.55Ω to 12Ω, R3 is 1 mΩ to 30 mΩ, and R4 is 1.1 mΩ to 30 mΩ.

### Claim 4 (depends on 1)

The secondary battery according to claim 1, wherein a coating weight of a negative active material per unit area of the first negative active material layer is CW3, a coating weight of the negative active material per unit area of the second negative active material layer is CW4, wherein 5.2 mg/cm2<CW3≤19.5 mg/cm2, 5.2 mg/cm2≤CW4≤19.5 mg/cm2 and the coating weight satisfies 1≤CW3/CW4<1.5.

### Claim 5 (depends on 1)

The secondary battery according to claim 1, wherein a compacted density of the first positive active material layer and/or the second positive active material layer is 2.0 g/cm3 to 3.6 g/cm3, and a compacted density of the first negative active material layer and/or the second negative active material layer is 0.5 g/cm3 to 2 g/cm3.

### Claim 6 (depends on 5)

The secondary battery according to claim 5, wherein a compacted density of the first positive active material layer and/or the second positive active material layer is 2.3 g/cm3 to 3.5 g/cm3, and a compacted density of the first negative active material layer and/or the second negative active material layer is 1.0 g/cm3 to 1.8 g/cm3.

### Claim 7 (depends on 1)

The secondary battery according to claim 1, wherein the first positive active material layer and/or the second positive active material layer each independently contain at least one of an NCM ternary material, an NCA ternary material, lithium iron phosphate, lithium manganese oxide, lithium cobalt oxide, active-sodium-ion-containing oxide, a polyanion material, or a Prussian blue-based material.

### Claim 8 (depends on 1)

The secondary battery according to claim 1, wherein the first positive active material layer and/or the second positive active material layer each independently contain a conductive agent and a binder, the conductive agent is graphite, carbon black, acetylene black, graphene, carbon nanotubes, or a combination thereof, and the binder is selected from polyvinylidene difluoride, polyacrylic acid, polytetrafluoroethylene, polyimide, or a combination thereof.

### Claim 9 (depends on 1)

The secondary battery according to claim 1, wherein the first negative active material layer and/or the second negative active material layer each independently contain natural graphite, artificial graphite, graphene, carbon nanotubes, soft carbon, hard carbon, or a combination of two or more thereof.

### Claim 10 (depends on 1)

A battery module, comprising the secondary battery according to claim 1.

### Claim 11 (depends on 1)

A battery pack, comprising the secondary battery according to claim 1.

### Claim 12 (depends on 1)

An electrical device, comprising the secondary battery according to claim 1.
