# US 12,215,609 B2 · Plant and process for energy generation and storage > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 12,215,609 B2 - Document ID: US12215609B2 - Status: Granted - Kind: B2 - Application number: 18/469,183 - Filed: 2023-09-18 - Published: 2024-01-04 - Granted: 2025-02-04 - Earliest claimed: 2020-03-24 - Assignees: Energy Dome S.P.A. - Applicants: Energy Dome S.P.A. - Inventors: Claudio Spadacini - Web page: https://patentgrep.com/patent/US12215609B2 ## CPC - F01K 25/103: {Carbon dioxide (F01K25/065 takes precedence)} - F01K 3/18: having heaters (having both steam accumulator and heater F01K3/14; steam heaters per se F22) - F02C 6/14: Gas-turbine plants having means for storing energy, e.g. for meeting peak loads - Y02E 60/14: Thermal energy storage - F01K: STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES (gas-turbine or jet-propulsion plants F02; nuclear power plants, engine arrangements therein G21D) - F02C: GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS (construction of turbines F01D; jet-propulsion plants F02K; construction of compressors or fans F04; generating combustion products of high pressure or high velocity F23R; using gas turbines in compression refrigeration plants F25B11/00) - Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION ## Abstract A plant for storing energy includes a casing for the storage of a working fluid other than atmospheric air, in gaseous phase and in equilibrium of pressure with the atmosphere; and a tank for the storage of the working fluid in liquid or supercritical phase with a temperature close to the critical temperature. The plant is configured to perform a closed cyclic thermodynamic transformation, first in one direction in a charge configuration and then in an opposite direction in a discharge configuration, between the casing and the tank. In the charge configuration, the plant stores heat and pressure and in the discharge configuration the plant generates energy. The plant is also configured to define a closed circuit and to perform a closed thermodynamic cycle in the closed circuit with at least a part of the working fluid. ## Claims ### Claim 1 A process for energy generation and storage, comprising: carrying out a closed cyclic thermodynamic transformation through a working fluid different from atmospheric air; the closed thermodynamic cyclic transformation being carried out first in one direction in a charge phase and then in an opposite direction in a discharge phase; the closed thermodynamic cyclic transformation being carried out between a casing and a tank; wherein, in the charge phase, the working fluid stored in the casing in a gaseous phase and in pressure equilibrium with the atmosphere, is compressed, cooled and stored in the tank in a liquid or supercritical phase with a temperature close to the critical temperature; wherein, in the charge phase, the process accumulates heat and pressure, wherein the charge phase comprises: compressing in a compressor said working fluid coming from said casing, the casing being externally in contact with the atmosphere and delimiting at the interior thereof a volume configured to contain the working fluid at atmospheric pressure or substantially atmospheric, wherein energy is absorbed while compressing the working fluid; introducing the compressed working fluid through a primary heat exchanger and a secondary heat exchanger placed in series to bring a temperature of the working fluid close to its own critical temperature; wherein the primary heat exchanger works as a cooler to remove heat from the compressed working fluid, cool the compressed working fluid and store thermal energy, wherein the secondary heat exchanger works as a cooler to remove further heat from the compressed working fluid and store further thermal energy; and accumulating the cooled working fluid in said tank; wherein the secondary heat exchanger and the primary heat exchanger carry out a super-critical transformation of the working fluid so that said working fluid is accumulated in the tank in the super-critical phase or wherein the secondary heat exchanger and the primary heat exchanger carry out a sub-critical transformation of the working fluid so that said working fluid is accumulated in the tank in the liquid phase; wherein, in the discharge phase, the working fluid stored in the tank in the liquid or supercritical phase is heated, expanded and returned to the casing in the gaseous phase and in pressure equilibrium with the atmosphere; wherein, in the discharge phase, the process generates energy, wherein the discharge phase comprises: passing the working fluid, coming from the tank, through the secondary heat exchanger and the primary heat exchanger; wherein the secondary heat exchanger works as a heater to transfer heat to the working fluid coming from the tank, wherein the primary heat exchanger works as a heater to transfer further heat to the working fluid and heat the working fluid; passing the heated working fluid through a turbine. wherein the turbine is rotated by the heated working fluid and drives at least one of a generator and a driven machine, generating energy, wherein the working fluid expands and cools down in the turbine; and re-introducing the working fluid coming from the turbine into the casing at the atmospheric or substantially atmospheric pressure; wherein the process further comprises: carrying out, with at least a part of said working fluid, a closed thermodynamic cycle in a closed circuit, wherein the closed thermodynamic cycle comprises: compressing at least a part of said working fluid into the compressor; passing said at least a part of said working fluid through a further heat exchanger operatively associated with an additional heat source; expanding said at least a part of said heated working fluid through the turbine, wherein the turbine is rotated by the heated working fluid and drives the generator or the driven machine, generating energy, wherein the working fluid expands and cools in the turbine; cooling said at least a part of said working fluid in an additional heat exchanger and re-introducing said at least a part of said working fluid into the compressor, wherein the closed circuit for actuation of the closed thermodynamic cycle passes through: the compressor, the further heat exchanger, the turbine and the additional heat exchanger, and wherein the closed circuit comprises a first bypass conduit connecting an outlet of the compressor with the further heat exchanger and bypassing the primary heat exchanger and the tank, and a second bypass conduit connecting an outlet of the turbine with an inlet of the compressor and bypassing the casing. ### Claim 2 (depends on 1) The process according to claim 1, wherein the compression of the working fluid in the compressor is inter-cooled. ### Claim 3 (depends on 1) The process according to claim 1, wherein the closed thermodynamic cycle has a higher pressure and a lower pressure; wherein the higher pressure is equal to or lower than the maximum pressure of the cyclic thermodynamic transformation in the charge phase; wherein the lower pressure is equal to or higher than the minimum pressure of the cyclic thermodynamic transformation in the discharge phase. ### Claim 4 (depends on 1) The process according to claim 1, wherein said part of the working fluid operating according to the closed thermodynamic cycle is between 0% and 50% of said working fluid. ### Claim 5 (depends on 1) The process according to claim 1, wherein said working fluid has the following physical-chemical properties: critical temperature between 0° C. and 200° C., density at 25° C. and at ambient pressure between 0.5 kg/m3 and 10 kg/m3. ### Claim 6 (depends on 1) The process according to claim 1, wherein an expansion of the working fluid in the turbine is inter-heated. ### Claim 7 (depends on 1) The process according to claim 1, comprising: increasing the pressure in the discharge phase by means of a pump placed between the secondary heat exchanger and the primary heat exchanger. ### Claim 8 (depends on 1) The process according to claim 1, comprising: adjusting a flow of the working fluid in the closed thermodynamic cycle by throttling a first valve on the first bypass conduit and by throttling a second valve on the second bypass conduit. ### Claim 9 (depends on 4) The process according to claim 4 wherein a remaining part of the working fluid accumulated in the tank or in the casing is between 100% and 50% of said working fluid. ### Claim 10 (depends on 1) The process according to claim 1, wherein the working fluid is chosen in the group including: CO2, SF6, N2O. ### Claim 11 (depends on 1) The process according to claim 1, wherein the closed thermodynamic cycle in the closed circuit is carried out simultaneously with the charge phase or with the discharge phase. ### Claim 12 (depends on 1) The process according to claim 1, wherein the closed thermodynamic cycle is a Brayton cycle. ### Claim 13 (depends on 1) The process according to claim 1, wherein the closed thermodynamic cycle operates with a net flow of the working fluid from and towards the tank and the casing at high and low pressure that is negligible or zero. ### Claim 14 (depends on 1) The process according to claim 1, wherein the closed thermodynamic cycle is that of a prime mover and produces at least one of electrical and mechanical energy. ### Claim 15 (depends on 1) The process according to claim 1, wherein the closed thermodynamic cycle is that of a heat pump and generates and releases heat. ### Claim 16 A process for energy generation and storage, comprising: carrying out a closed cyclic thermodynamic transformation through a working fluid different from atmospheric air; the closed thermodynamic cyclic transformation being carried out first in one direction in a charge phase and then in an opposite direction in a discharge phase; the closed thermodynamic cyclic transformation being carried out between a casing and a tank; wherein, in the charge phase, the working fluid stored in the casing in a gaseous phase and in pressure equilibrium with the atmosphere, is compressed, cooled and stored in the tank in a liquid or supercritical phase with a temperature close to the critical temperature; wherein, in the charge phase, the process accumulates heat and pressure; wherein the charge phase comprises: compressing in a compressor said working fluid coming from said casing, the casing being externally in contact with the atmosphere and delimiting at the interior thereof a volume configured to contain the working fluid at atmospheric pressure or substantially atmospheric, wherein energy is absorbed while compressing the working fluid; introducing the compressed working fluid through a primary heat exchanger and a secondary heat exchanger placed in series to bring a temperature of the working fluid close to its own critical temperature; wherein the primary heat exchanger works as a cooler to remove heat from the compressed working fluid, cool the compressed working fluid and store thermal energy, wherein the secondary heat exchanger works as a cooler to remove further heat from the compressed working fluid and store further thermal energy; and accumulating the cooled working fluid in said tank; wherein the secondary heat exchanger and the primary heat exchanger carry out a super-critical transformation of the working fluid so that said working fluid is accumulated in the tank in the super- critical phase or wherein the secondary heat exchanger and the primary heat exchanger carry out a sub-critical transformation of the working fluid so that said working fluid is accumulated in the tank in the liquid phase; wherein, in the discharge phase, the working fluid stored in the tank in the liquid or supercritical phase is heated, expanded and returned to the casing in the gaseous phase and in pressure equilibrium with the atmosphere; wherein, in the discharge phase, the process generates energy; wherein the discharge phase comprises: passing the working fluid, coming from the tank, through the secondary heat exchanger and the primary heat exchanger; wherein the secondary heat exchanger works as a heater to transfer heat to the working fluid coming from the tank, wherein the primary heat exchanger works as a heater to transfer further heat to the working fluid and heat the working fluid; passing the heated working fluid through a turbine, wherein the turbine is rotated by the heated working fluid and drives at least one of a generator and a driven machine, generating energy, wherein the working fluid expands and cools down in the turbine; and re-introducing the working fluid coming from the turbine into the casing at the atmospheric or substantially atmospheric pressure; wherein the process further comprises: carrying out, with at least a part of said working fluid, a closed thermodynamic cycle in a closed circuit; and wherein the process further comprises: increasing the pressure in the discharge phase by means of a pump placed between the secondary heat exchanger and the primary heat exchanger. ### Claim 17 A process for energy generation and storage, comprising: carrying out a closed cyclic thermodynamic transformation through a working fluid different from atmospheric air; the closed thermodynamic cyclic transformation being carried out first in one direction in a charge phase and then in an opposite direction in a discharge phase; the closed thermodynamic cyclic transformation being carried out between a casing and a tank; wherein, in the charge phase, the working fluid stored in the casing in a gaseous phase and in pressure equilibrium with the atmosphere, is compressed in a compressor, cooled through a primary heat exchanger and a secondary heat exchanger working as coolers and stored in the tank in a liquid or supercritical phase with a temperature close to the critical temperature; wherein, in the charge phase, the process accumulates heat and pressure and the primary heat exchanger and secondary heat exchanger store thermal energy; wherein, in the discharge phase, the working fluid stored in the tank in the liquid or supercritical phase is heated through the primary heat exchanger and the secondary heat exchanger working as heaters, expanded in a turbine and returned to the casing in the gaseous phase and in pressure equilibrium with the atmosphere; wherein, in the discharge phase, the process generates energy through the turbine; wherein the process further comprises: carrying out, with at least a part of said working fluid, a closed thermodynamic cycle in a closed circuit; wherein the closed circuit for actuation of the closed thermodynamic cycle passes through: the compressor, a further heat exchanger, the turbine and an additional heat exchanger; and wherein the closed circuit comprises: a first bypass conduit connecting an outlet of the compressor with the further heat exchanger and bypassing the primary heat exchanger and the tank; a second bypass conduit connecting an outlet of the turbine with an inlet of the compressor and bypassing the casing. ### Claim 18 (depends on 17) The process according to claim 17, wherein the charge phase comprises: compressing in the compressor said working fluid coming from said casing, the casing being externally in contact with the atmosphere and delimiting at the interior thereof a volume configured to contain the working fluid at atmospheric pressure or substantially atmospheric, wherein energy is absorbed while compressing the working fluid; introducing the compressed working fluid through the primary heat exchanger and the secondary heat exchanger placed in series to bring a temperature of the working fluid close to its own critical temperature; wherein the primary heat exchanger works as a cooler to remove heat from the compressed working fluid, cool the compressed working fluid and store thermal energy, wherein the secondary heat exchanger works as a cooler to remove further heat from the compressed working fluid and store further thermal energy; accumulating the cooled working fluid in said tank; wherein the secondary heat exchanger and the primary heat exchanger carry out a super-critical transformation of the working fluid so that said working fluid is accumulated in the tank in the super-critical phase or wherein the secondary heat exchanger and the primary heat exchanger carry out a sub-critical transformation of the working fluid so that said working fluid is accumulated in the tank in the liquid phase. ### Claim 19 (depends on 18) The process according to claim 18, wherein the discharge phase comprises: passing the working fluid, coming from the tank, through the secondary heat exchanger and the primary heat exchanger; wherein the secondary heat exchanger works as a heater to transfer heat to the working fluid coming from the tank, wherein the primary heat exchanger works as a heater to transfer further heat to the working fluid and heat the working fluid; passing the heated working fluid through the turbine, wherein the turbine is rotated by the heated working fluid and drives at least one of a generator and a driven machine, generating energy, wherein the working fluid expands and cools down in the turbine; re-introducing the working fluid coming from the turbine into the casing at the atmospheric or substantially atmospheric pressure. ### Claim 20 (depends on 19) The process according to claim 19, wherein the closed thermodynamic cycle comprises: compressing at least a part of said working fluid into the compressor; passing said at least a part of said working fluid through the further heat exchanger operatively associated with an additional heat source; expanding said at least a part of said heated working fluid through the turbine, wherein the turbine is rotated by the heated working fluid and drives the generator or the driven machine, generating energy, wherein the working fluid expands and cools in the turbine; cooling said at least a part of said working fluid in the additional heat exchanger and re-introducing said at least a part of said working fluid into the compressor.