# US 12,215,059 B2 · Activation of ground granulated blast furnace slag

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- Number: US 12,215,059 B2
- Document ID: US12215059B2
- Status: Granted
- Kind: B2
- Application number: 17/281,153
- Filed: 2019-10-01
- Published: 2021-11-04
- Granted: 2025-02-04
- Earliest claimed: 2018-10-02
- Assignees: Sika Technology AG
- Applicants: Sika Technology AG
- Inventors: Lissa Dupouy; Maxime Liard; Lolita Hauguel; Didier Lootens
- Web page: https://patentgrep.com/patent/US12215059B2

## CPC

- C04B 28/08: Slag cements
- C04B 7/02: Portland cement
- C04B 22/064: {of the alkaline-earth metals}
- C04B 22/10: containing carbon in the anion, e.g. carbonates
- C04B 22/106: {Bicarbonates}
- C04B 22/143: {Calcium-sulfate}
- C04B 22/147: {Alkali-metal sulfates; Ammonium sulfate}
- C04B 2103/12: Set accelerators
- C04B 2103/14: Hardening accelerators
- C04B 2103/32: Superplasticisers
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE

## Abstract

An improved mineral binder composition including: a mineral binder including at least 30 weight-% slag, based on the weight of the mineral binder, an activator for the hydration of the slag consisting of or comprising calcium hydroxide and a co-activator consisting of or including at least one salt selected from the group consisting of lithium carbonate, lithium sulfate and sodium carbonate.

## Claims

### Claim 1

A mineral binder composition comprising:
a mineral binder comprising 36-65 weight-% of slag and 35-64 weight-% of Portland cement, based on the weight of the mineral binder,
an activator for the hydration of the slag comprising calcium hydroxide and
a co-activator comprising at least one salt selected from the group consisting of lithium carbonate, lithium sulfate and sodium carbonate,
wherein the activator is present in an amount in a range of 0.5-3.0 weight-% based on the weight of the mineral binder,
wherein the co-activator is present in an amount in a range of 0.16-0.8 weight-% based on the weight of the mineral binder, and
wherein a weight-ratio of activator to co-activator is 10:1 to 1.1:1.

### Claim 2 (depends on 1)

The mineral binder composition according to claim 1, wherein the slag has a specific surface of 4,400 to 6,000 cm2/g, measured by the Blaine method.

### Claim 3 (depends on 1)

The mineral binder composition according to claim 1, wherein the co-activator comprises lithium carbonate and/or sodium carbonate.

### Claim 4 (depends on 1)

The mineral binder composition according to claim 1, wherein the co-activator consists of lithium carbonate and/or sodium carbonate.

### Claim 5 (depends on 1)

The mineral binder composition according to claim 1, further comprising 0.1 to 5 weight-%, calcium sulfate, based on the weight of the mineral binder without calcium sulfate.

### Claim 6 (depends on 1)

The mineral binder composition according to claim 1, further comprising a superplasticizer.

### Claim 7 (depends on 1)

The mineral binder composition according to claim 1, wherein
the activator is calcium hydroxide
the co-activator is lithium carbonate and/or sodium carbonate and the mineral binder composition further comprises,
0 to 4 weight-% of at least one superplasticizer,
0 to 5 weight-% calcium sulfate,
0.006 to 0.5 weight-% of a viscosity-enhancing agent, and
0 to 3 weight-% further additives,
wherein all weight-% are based on the weight of the mineral binder.

### Claim 8 (depends on 1)

A method for accelerating setting and/or hardening of the mineral binder of claim 1, comprising adding a composition comprising, based on the weight of the composition,
5 to 95 weight-% calcium hydroxide,
5 to 60 weight-% lithium carbonate, lithium sulfate or sodium carbonate,
0 to 40 weight-% calcium sulfate,
0 to 35 weight-% superplasticizer,
0 to 20 weight-% viscosity-enhancing agent, and
0 to 20 weight-% further additives
to the mineral binder.

### Claim 9 (depends on 1)

A hardened body obtained after hardening of the mineral binder composition according to claim 1 after mixing with water.
