# US 12,214,098 B2 · Catalyst for generating hydrogen peroxide induced by temperature difference and method for environmental disinfection using same

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- Number: US 12,214,098 B2
- Document ID: US12214098B2
- Status: Granted
- Kind: B2
- Application number: 17/522,875
- Filed: 2021-11-09
- Published: 2023-02-16
- Granted: 2025-02-04
- Earliest claimed: 2021-08-16
- Assignees: National Tsing Hua University
- Applicants: National Tsing Hua University
- Inventors: Zong-Hong Lin; Yu-Jiung Lin; Imran Khan
- Web page: https://patentgrep.com/patent/US12214098B2

## CPC

- A61L 2/208: Hydrogen peroxide
- A61L 2/26: Accessories
- A61L 9/015: using gaseous or vaporous substances, e.g. ozone (A61L9/20 takes precedence {; evaporation in general B01B1/005})
- B01J 21/063: {Titanium; Oxides or hydroxides thereof}
- B01J 27/0573: {Selenium; Compounds thereof}
- B01J 27/0576: {Tellurium; Compounds thereof}
- B01J 31/06: containing polymers {(organometallic polymers B01J31/123; polymer-bound organometallic complexes B01J31/165; coordination polymers B01J31/1691)}
- B01J 35/39: Photocatalytic properties
- B01J 35/54: Bars or plates
- A61L 2103/50: Textiles, e.g. bedwear or towels
- A61L 2103/75: Room floors or walls
- A61L 2202/11: Apparatus for generating biocidal substances, e.g. vaporisers, UV lamps
- A61L 2209/211: Use of hydrogen peroxide, liquid and vaporous
- B01J 2235/00: Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J 2235/15: X-ray diffraction
- B01J 2235/30: Scanning electron microscopy; Transmission electron microscopy
- A61L: METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES (preservation of bodies or disinfecting characterised by the agents employed A01N; preserving, e.g. sterilising, food or foodstuffs A23; preparations for medical, dental or toiletry purposes A61K)
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

## Abstract

A catalyst adapted for generating hydrogen peroxide induced by a temperature difference and a method for environmental disinfection using the same are provided. The catalyst includes a thermoelectric material distributed on a substrate. The thermoelectric material induces a reaction between water vapor and oxygen contained in the air through a temperature difference to generate hydrogen peroxide, to serve a sterilization function through the hydrogen peroxide generated. The method for environmental disinfection using the catalyst includes the following. The catalyst is placed in an environment with a temperature difference. The catalyst is caused to induce a reaction between water vapor and oxygen contained in air through the temperature difference to generate hydrogen peroxide without applying power, and serve a sterilization function through the hydrogen peroxide generated.

## Claims

### Claim 1

A catalyst for generating hydrogen peroxide induced by a temperature difference, the catalyst comprising:
a plurality of thermoelectric materials, being distributed on a substrate and inducing a reaction between water vapor and oxygen contained in air through a temperature difference to generate hydrogen peroxide (H2O2) to serve a sterilization function through the hydrogen peroxide generated,
wherein in a top view, the plurality of thermoelectric materials are independently dispersed on the substrate.

### Claim 2 (depends on 1)

The catalyst as described in claim 1, wherein a form of the thermoelectric material comprises a nanomaterial or a bulk.

### Claim 3 (depends on 2)

The catalyst as described in claim 2, wherein the nanomaterial comprises a nanoparticle, a nanoplate, or a nanowire.

### Claim 4 (depends on 1)

The catalyst as described in claim 1, wherein the thermoelectric material is at least one material selected from a group consisting of a metal composite oxide, a polymer, a silicide, skutterudite, a Half-Heusler alloy, and a compound containing tellurium (Te).

### Claim 5 (depends on 4)

The catalyst as described in claim 4, wherein the thermoelectric material comprises bismuth telluride (Bi2Te3), antimony telluride (Sb2Te3), or lead telluride (PbTe).

### Claim 6 (depends on 1)

The catalyst as described in claim 1, wherein the substrate comprises a sheet substrate, a porous substrate, or a mesh substrate.

### Claim 7 (depends on 1)

The catalyst as described in claim 1, wherein a concentration of the hydrogen peroxide generated is modulated through a content of the thermoelectric material and/or a magnitude of the temperature difference.

### Claim 8 (depends on 1)

The catalyst as described in claim 1, wherein the thermoelectric material is formed on the substrate by coating, spraying, or soaking.

### Claim 9

A method for environmental disinfection comprising:
providing a catalyst for generating hydrogen peroxide induced by a temperature difference, wherein the catalyst comprises:
a plurality of thermoelectric materials being distributed on a substrate, wherein in a top view, the plurality of thermoelectric materials are independently dispersed on the substrate;
placing the catalyst in an environment with the temperature difference; and
causing the catalyst to induce a reaction between water vapor and oxygen contained in air through the temperature difference to generate the hydrogen peroxide without applying power, and serve a sterilization function through the hydrogen peroxide generated.

### Claim 10 (depends on 9)

The method as described in claim 9, wherein the environment with the temperature difference comprises an air outlet of an air conditioner, a heater, a fan, or a stove.

### Claim 11 (depends on 9)

The method as described in claim 9, wherein the environment with the temperature difference comprises a surface of a mask.

### Claim 12 (depends on 9)

The method as described in claim 9, wherein the environment with the temperature difference comprises an exterior wall or a window of a building.
