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US 12,203,023 B2Granted
Aromatic isothiocyanates
AssigneeMerck Patent GmbH
InventorsConstanze Brocke, Dagmar Klass, Carsten Fritzsch
Life of this patent
Estimating the term…
Abstract
The present invention relates to a compound of formula GF in which the occurring groups and parameters have the meanings defined in claim 1, to a liquid crystal medium comprising a compound of formula GF and to high-frequency components comprising these media, especially microwave components for high-frequency devices, such as devices for shifting the phase of microwaves, tunable filters, tunable metamaterial structures, and electronic beam steering antennas, e.g. phased array antennas.
Claims20
A compound of formula GF
- in which
- RG denotes H, straight-chain, non-fluorinated alkyl or alkoxy having 1 to 12 C atoms, branched, non-fluorinated alkyl or alkoxy having 3 to 12 C atoms, straight-chain, non-fluorinated alkenyl having 2 to 12 C atoms, or branched, non-fluorinated alkenyl having 2-3 to 12 C atoms, in each of which one or more CH2— groups may each be replaced by
- or a group RP,
- RP denotes halogen, CN, NCS, RF-, RF-O— or RF-S—, wherein
- RF denotes fluorinated alkyl having 1 to 9 C atoms,
- ZG1, ZG2 identically or differently, denote —CH═CH—, —CF═CF—, —CH—CF—, —CF═CH—, —C≡C—, —C≡C≡C≡C— or a single bond,
- XG1, XG2, identically or differently, denote Cl or F,
- identically or differently, denote a radical selected from the following groups:
- a) the group consisting of 1,4-phenylene, 1,4-naphthylene, and 2,6-naphthylene, in which one or two CH groups may each be replaced by N and in which one or more H atoms may each be replaced by L,
- b) the group consisting of trans-1,4-cyclohexylene, 1,4-cyclohexenylene, tetralin-2,6-diyl, tetralin-5,8-diyl, decalin-2,6-diyl, bicyclo[1.1.1]pentane-1,3-diyl, 4,4′-bicyclohexylene, bicyclo[2.2.2]octane-1,4-diyl, and spiro [3.3]-heptane-2,6-diyl, in which one or two CH groups may each be replaced by N, one or more non-adjacent CH2 groups may each be replaced by —O— and/or —S— and in which one or more H atoms may each be replaced by L, and
- c) the group consisting of thiophene-2,5-diyl, thieno [3,2-b]thiophene-2,5-diyl, and selenophene-2,5-diyl, each of which may also be mono- or polysubstituted by L,
- L on each occurrence, identically or differently, denotes F, CI, CN, SCN, SF5, straight-chain optionally fluorinated alkyl or alkoxy having 1 to 12 C atoms, branched optionally fluorinated alkyl or alkoxy having 3 to 12 C atoms, straight-chain optionally fluorinated alkylcarbonyl having 2 to 12 C atoms, branched optionally fluorinated alkylcarbonyl having 4 to 12 C atoms, straight-chain optionally fluorinated alkoxycarbonyl having 2 to 12 C atoms, branched optionally fluorinated alkoxy-carbonyl having 4 to 12 C atoms, straight-chain optionally fluorinated alkyl-carbonyloxy having 2 to 12 C atoms, branched optionally fluorinated alkyl-carbonyloxy having 4 to 12 C atoms, straight-chain optionally fluorinated alkoxycarbonyloxy having 2 to 12 C atoms, or branched optionally fluorinated alkoxycarbonyloxy having 4 to 12 C atoms, and
- u is 0, 1 or 2,
- wherein at least one of
- is not trans-1,4-cyclohexylene.
12 more elements
Dependencies are inferred from the claim text.