Organopolysiloxane composition for use in release paper or release film
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsToshiaki Ihara, Kenji Tanaka, Ataru Kobayashi
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Abstract
In the present invention, compounding an addition-reaction-curable organopolysiloxane composition with a specific amount of an organopolysiloxane compound that has three or more (meth)acryl groups in the molecule and a weight-average molecular weight of 1,000 or greater yields an organopolysiloxane composition for use in a release paper or release film in which addition reactions can occur using a small amount of platinum family metal catalyst, cured films can be formed having a peeling strength approximating levels encountered in the past, and addition-reaction-prompted curing will proceed even on a base material containing a catalyst-poisoning component.
Claims7
An organopolysiloxane composition for release paper or release film consisting of the following components (A) to (D):
- (A) an organopolysiloxane having at least two silicon-bonded alkenyl groups per molecule, but not at least three (meth)acrylic groups,
- (B) an organohydrogenpolysiloxane having on the average at least two silicon-bonded hydrogen atoms (i.e., Si—H groups) per molecule, but not at least three (meth)acrylic groups, in such an amount that the moles of Si—H groups in component (B) is 1 to 5 times the moles of alkenyl groups in component (A),
- (C) an organopolysiloxane compound having at least three (meth)acrylic groups per molecule and represented by the general formula (3)
- MiaM1AbD1cD1AdT1eT1AfQ1g (3)
- wherein M1 is R13SiO1/2, M1A is R12ASIO1/2, D1 is R2SiO2/2, D1A is R1ASIO2/2, T1 is R1SiO3/2, T1A is ASiO3/2, and Q1 is SiO4/2,
- R1 is each independently a C1-C18 unsubstituted or substituted monovalent hydrocarbon group, or alkoxy group, hydroxy group, epoxy group, or polyoxyalkylene group,
- wherein in the groups R12ASiO1/2, R1ASIO2/2, and ASiO3/2, A is CH2═CR2COR3—,
- R2 is hydrogen or methyl,
- R3 is OR4 or R4,
- R4 is a C1-C20 divalent group which may have a branched or cyclic structure and may contain an epoxy group, ester bond, urethane bond, ether bond, isocyanate bond, or hydroxy group,
- the subscript a is an integer of 0 to 10,
- the subscript b is an integer of 0 to 5, wherein b is an integer of 2 to 5 when a is 0, and b is an integer of 1 to 5 when a is 1,
- the subscript c is an integer of 5 to 300,
- the subscript d is an integer of 3 to 200,
- the subscripts e and f each are an integer of 0 to 10, and
- the subscript g is 0 or 1;
- and
- wherein the organopolysiloxane compound has a weight average molecular weight of at least 1,000, in an amount of 0.01 to 5 parts by weight per 100 parts by weight of component (A), and
- (D) a platinum group metal base catalyst in an amount to give a platinum concentration of 1 to 100 ppm by weight based on the total weight of components (A), (B), (C), and (D), and optionally further consisting of one or more of:
- (E) a reaction inhibitor,
- organic solvent,
- aryl group-containing silicone resins other than components (A) to (C), and silica.
Dependencies are inferred from the claim text.