Method for removing ammonia from non-condensable gases of a pulp mill
AssigneeValmet Technologies Oy
InventorsNaveen Chenna, Tero Juutilainen
Life of this patent
Estimating the term…
Abstract
A method for removing ammonia (NH3) from a gas produced in a pulp mill (100). The method comprises producing raw non-condensable gas comprising ammonia (NH3) in the pulp mill (100) and transferring at least some of the raw non-condensable gas to a scrubber (200) containing aqueous scrubbing solution (130, 140). The method comprises adding a compound capable of decreasing a pH of the scrubbing solution to the scmbbing solution (130, 140) and in the scrubber (200), contacting the raw non-condensable gas with the scmbbing solution (130, 140), to react the ammonia (NH3) of the raw non-condensable gas with the scmbbing solution to produce clean non-condensable gas and ammonium (NH4+). A pulp mill comprising equipment for performing the method.
Claims15
A method for removing ammonia (NH3) from a gas produced in a pulp mill, the method comprising:
- producing raw non-condensable gas comprising ammonia (NH3) in the pulp mill,
- transferring at least some of the raw non-condensable gas to a scrubber containing aqueous scrubbing solution,
- in the scrubber, contacting the raw non-condensable gas with the scrubbing solution, to react the ammonia (NH3) of the raw non-condensable gas with the scrubbing solution to produce clean non-condensable gas and foul condensate comprising ammonium (NH4+),
- adding a compound capable of decreasing a pH of the scrubbing solution to the scrubbing solution,
- measuring a pH of the scrubbing solution,
- controlling a pH of the scrubbing solution based on the measured pH value by controlling a flow of the compound capable of decreasing a pH of the scrubbing solution to the scrubber,
- in the scrubber, spraying the scrubbing solution to form droplets of the scrubbing solution,
- contacting the non-condensable gas comprising ammonia with the droplets of the scrubbing solution,
- conveying the foul condensate from the scrubber to a stripper,
- stripping the foul condensate to produce clean condensate,
- conveying the clean condensate to a pulp bleaching area,
- bleaching pulp in the pulp bleaching area using the clean condensate to produce bleached pulp and bleaching effluent,
- conveying the bleaching effluent to a wastewater treatment area, and
- purifying water in the wastewater treatment area using the bleaching effluent,
- wherein:
- the bleaching effluent comprises ammonium (NH4+),
- the compound capable of decreasing a pH of the scrubbing solution comprises sulfuric acid (H2SO4) and
- a pH of the scrubbing solution is from 4.5 to 5.5.
Dependencies are inferred from the claim text.