Coated part comprising a protective coating based on MAX phases
AssigneeSafran
InventorsAurélien Joulia, Pierre Jean Sallot
Life of this patent
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Abstract
A coated part includes a metallic substrate, a thermal barrier comprising a ceramic material and covering the metallic substrate, wherein the coated part further includes a protective coating covering the thermal barrier, the protective coating including, in a first region, a first MAX phase, denoted PZ2, of formula (ZrxTi1-x)2AlC or a first MAX phase, denoted PC2, of formula (CrxTi1-x)2AlC with x non-zero and less than or equal to 1 in the MAX phases PZ2 and PC2, and the protective coating includes, in a second region covering the first region, a second MAX phase of formula Ti2AlC.
Claims19
A coated part comprising:
- a metallic substrate being a nickel-based or cobalt-based superalloy,
- a thermal barrier covering the metallic substrate and comprising (a) a bonding layer containing an alloy MCrAlY with M designating nickel, cobalt or a nickel-cobalt combination, or a nickel aluminide and (b) a ceramic layer covering the bonding layer,
- wherein the coated part further comprises a protective coating covering the thermal barrier, the protective coating comprising, in a first region, a first MAX phase, denoted PZ2, of formula (ZrxTi1-x)2AlC or a first MAX phase, denoted PC2, of formula (CrxTi1-x)2AlC with x non-zero and less than or equal to 1 in the MAX phases PZ2 and PC2, and the protective coating comprising, in a second region covering the first region, a second MAX phase of formula Ti2AlC.
A coated part comprising:
- a metallic substrate being a nickel-based or cobalt-based superalloy,
- a thermal barrier covering the metallic substrate and comprising (a) a bonding layer containing an alloy MCrAlY with M designating nickel, cobalt or a nickel-cobalt combination, or a nickel aluminide and (b) a ceramic layer covering the bonding layer,
- wherein the coated part further comprises a protective coating covering the thermal barrier, the protective coating comprising, in a first region, a first MAX phase, denoted PZ3, of formula (ZrxTi1-x)3AlC2 or a first MAX phase, denoted PC3, of formula (CrxTi1-x)3AlC2 with x non-zero and less than or equal to 1 in the MAX phases PZ3 and PC3, and the protective coating comprising, in a second region covering the first region, a second MAX phase of formula Ti3AlC2.
A method for manufacturing a coated part comprising a metallic substrate,
- a thermal barrier comprising a ceramic material and covering the metallic substrate, wherein the coated part further comprises a protective coating covering the thermal barrier, the protective coating comprising, in a first region, a first MAX phase, denoted PZ2, of formula (ZrxTi1-x)2AlC or a first MAX phase, denoted PC2, of formula (CrxTi1-x)2AlC with x non-zero and less than or equal to 1 in the MAX phases PZ2 and PC2, and the protective coating comprising, in a second region covering the first region, a second MAX phase of formula Ti2AlC and with x less than 1 in the MAX phases PZ2 and PC2,
- the method comprising, when the first region comprises the first MAX phase PZ2:
- depositing zirconium or a zirconium alloy on the thermal barrier, the deposit being made by a spray technique, by a vapour phase deposition technique, by sol-gel route or electrophoresis,
- depositing the second MAX phase of formula Ti2AlC on the previously deposited zirconium or zirconium alloy, the deposit being made by a spray technique, by a vapour phase deposition technique, by sol-gel route or electrophoresis, and
- a heat treatment for zirconium diffusion into the second MAX phase of formula Ti2AlC by imposing a temperature greater than or equal to 900° C. in order to obtain the coated part,
- or the method comprising, when the first region comprises the first MAX phase PC2:
- depositing chromium or a chromium alloy on the thermal barrier, the deposit being made by a spray technique, by a vapour phase deposition technique, by sol-gel route or electrophoresis, depositing the second MAX phase of formula Ti2AlC on the previously deposited chromium or chromium alloy, the deposit being made by a spray technique, by a vapour phase deposition technique, by sol-gel route or electrophoresis, and
- a heat treatment for chromium diffusion into the second MAX phase of formula Ti2AlC by imposing a temperature greater than or equal to 900° C. in order to obtain the coated part.
A method for manufacturing a coated part, comprising a metallic substrate,
- a thermal barrier comprising a ceramic material and covering the metallic substrate,
- wherein the coated part further comprises a protective coating covering the thermal barrier, the protective coating comprising, in a first region, a first MAX phase, denoted PZ3, of formula (ZrxTi1-x)3AlC2 or a first MAX phase, denoted PC3, of formula (CrxTi1-x)3AlC2 with x non-zero and less than or equal to 1 in the MAX phases PZ3 and PC3, and the protective coating comprising, in a second region covering the first region, a second MAX phase of formula Ti3AlC2,
- the method comprising, when the first region comprises the first MAX phase PZ3:
- depositing zirconium or a zirconium alloy on the thermal barrier, the deposit being made by a spray technique, by a vapour phase deposition technique, by sol-gel route or electrophoresis,
- depositing the second MAX phase of formula Ti3AlC2 on the previously deposited zirconium or zirconium alloy, the deposit being made by a spray technique, by a vapour phase deposition technique, by sol-gel route or electrophoresis, and
- a heat treatment for zirconium diffusion into the second MAX phase of formula Ti3AlC2 by imposing a temperature greater than or equal to 900° C. in order to obtain the coated part, or the method comprising, when the first region comprises the first MAX phase PC3:
- depositing chromium or a chromium alloy on the thermal barrier, the deposit being made by a spray technique, by a vapour phase deposition technique, by sol-gel route or electrophoresis,
- depositing the second MAX phase of formula Ti3AlC2 on the previously deposited chromium or chromium alloy, the deposit being made by a spray technique, by a vapour phase deposition technique, by sol-gel route or electrophoresis, and
- a heat treatment for chromium diffusion into the second MAX phase of formula Ti3AlC2 by imposing a temperature greater than or equal to 900° C. in order to obtain the coated part.
Dependencies are inferred from the claim text.