Method for producing polyalkylene oxide
AssigneeSumitomo Seika Chemicals Co., Ltd.
InventorsYuika Imamura, Akira Kimura
Life of this patent
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Abstract
A method for producing a polyalkylene oxide includes step 1 of performing a polymerization reaction of an alkylene oxide in the presence or absence of a chain transfer agent to obtain a high-molecular-weight polyalkylene oxide; and step 2 of irradiating the high-molecular-weight polyalkylene oxide obtained in step 1 with radiation to obtain a polyalkylene oxide, wherein the amount of the chain transfer agent when used is less than 300 mass ppm relative to the alkylene oxide, and the high-molecular-weight polyalkylene oxide obtained in step 1 has a viscosity at 25° C. in a 1 mass % aqueous solution of 7500 mPa·s or more.
Claims6
A method for producing a polyethylene polyalkylene oxide, comprising
- step 1 of performing a polymerization reaction of an ethylene oxide in the presence or absence of a chain transfer agent to obtain a high-molecular-weight polyethylene oxide;
- and
- step 2 of irradiating the high-molecular-weight polyethylene oxide obtained in step 1 with radiation to obtain a polyethylene oxide;
- wherein
- the amount of the chain transfer agent when used is less than 300 mass ppm relative to the ethylene oxide, and
- the high-molecular-weight polyethylene oxide obtained in step 1 has a viscosity at 25° C. in a 1 mass % aqueous solution of 7500 mPa·s or more,
- the viscosity at 25° C. in a 1 mass % aqueous solution of the high-molecular-weight polyethylene oxide being a value measured by the following method:
- 6 g of the high-molecular-weight polyethylene oxide and 125 mL of isopropanol are added to a 1 L beaker;
- while the mixture is stirred at 300 to 400 rpm using a stirring blade, 594 g of ion-exchange water is added, followed by stirring for one minute;
- subsequently, the stirring speed is changed to 60 rpm, and stirring is continued for an additional 3 hours to obtain a 1% aqueous solution of polyethylene oxide;
- the aqueous solution is kept at 25° C., and the viscosity is measured using a rotational viscometer;
- and the obtained value is referred to as the viscosity at 25° C. in a 1% aqueous solution.
Dependencies are inferred from the claim text.