Olefins and methods for making the same
AssigneeAmyris, Inc.
InventorsNicholas Ohler, Karl Fisher, Jin Ki Hong
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Abstract
Provided herein are olefinic feedstocks derived from conjugated hydrocarbon terpenes (e.g., C10-C30 terpenes), methods for making the same, and methods for their use.
Claims12
A method comprising selectively hydrogenating, in two or more stages, a conjugated terpene comprising at least three olefinic bonds wherein two of the at least three olefinic bonds form a conjugated diene to make a composition comprising at least about 50% mono-olefinic species and about 20% or less di-olefinic species in a mixture of hydrogenated reaction products,
- wherein the hydrogenating comprises catalytic hydrogenation with a catalyst, a catalyst loading, a reaction temperature, and hydrogen pressure,
- wherein the catalyst, the catalyst loading, the reaction temperature, and the hydrogen pressure are selected so that less than about 10% of the molecules in an intermediate product have a conjugated diene moiety after the first hydrogenation stage.
A method comprising selectively hydrogenating, in two or more stages, a conjugated terpene comprising at least three olefinic bonds wherein two of the at least three olefinic bonds form a conjugated diene to make a composition comprising greater than 60% mono-olefinic species in a mixture of hydrogenated reaction products,
- wherein the hydrogenating comprises catalytic hydrogenation with a catalyst, a catalyst loading, and a reaction temperature or hydrogen pressure,
- wherein the catalyst, the catalyst loading, the reaction temperature, and the hydrogen pressure are selected so that less than about 10% of the molecules in an intermediate product have a conjugated diene moiety after the first hydrogenation stage.
Dependencies are inferred from the claim text.