Resist compositions and semiconductor fabrication methods using the same
AssigneeSamsung Electronics Co., Ltd.
InventorsThanh Cuong Nguyen, Daekeon Kim, Tsunehiro Nishi, Naoto Umezawa, Hyunwoo Kim
Life of this patent
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Abstract
Disclosed are resist compositions and semiconductor device fabrication methods wing the same. The resist composition comprises a hypervalent iodine compound of Chemical Formula 1 below. Wherein R1 to R7 are as defined herein.
Claims22
An extreme ultraviolet (EUV) resist composition comprising a hypervalent iodine compound of Chemical Formula 1,
- wherein:
- R1 is hydrogen, R8CO—, or R9SO2-,
- R2 is R10CO— or R11SO2-,
- R3, R4, R5, R6, and R7 are each independently a hydrogen, a halogen, a halogen-substituted C1 or C2 alkyl group, or a halogen-substituted C6 to C20 aryl group, and
- R8, R9, R10, and R11 are each independently a substituted or unsubstituted C1 or C2 alkyl group or a substituted or unsubstituted C6 to C20 aryl group
- wherein the resist composition further comprises:
- a quencher;
- and
- a polymer comprising a compound of Chemical Formula 2A or 2B:
- wherein R20, R21, and R22 are each independently hydrogen or a substituted or unsubstituted C1 to C15 alkyl group, and m is an integer between 10 and 1,000,000, or
- wherein m is an integer between 10 and 1,000, and n is an integer between 10 to 1,000, wherein the resist composition forms a layer when exposed to EUV light at a wavelength of about 10 nm to about 124 nm.
An extreme ultraviolet resist composition comprising a hypervalent iodine compound of Chemical Formula M3
An extreme ultraviolet (EUV) resist composition comprising a hypervalent iodine compound of Chemical Formula 1,
- wherein:
- R1 is hydrogen, —C(O)CH3, —C(O)CF3, or R9SO2-,
- R2 is —C(O)CF3, —C(O)CH3, or R11SO2-,
- R3, R4, R5, R6, and R7 are each independently a hydrogen, a halogen, a halogen-substituted C1 or C2 alkyl group, or a halogen-substituted C6 to C20 aryl group, and
- R8, R9, R10, and R11 are each independently a substituted or unsubstituted C1 or C2 alkyl group or a substituted or unsubstituted C6 to C20 aryl group
- wherein the resist composition further comprises:
- a quencher;
- and
- a polymer comprising a compound of Chemical Formula 2A or 2B:
- wherein R20, R21, and R22 are each independently hydrogen or a substituted or unsubstituted C1 to C15 alkyl group, and m is an integer between 10 and 1,000,000, or
- wherein m is an integer between 10 and 1,000, and n is an integer between 10 to 1,000, wherein the resist composition forms a layer when exposed to EUV light at a wavelength of about 10 nm to about 124 nm.
Dependencies are inferred from the claim text.