# US 12,181,771 B2 · Transmissive liquid crystal diffraction element > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 12,181,771 B2 - Document ID: US12181771B2 - Status: Granted - Kind: B2 - Application number: 18/192,498 - Filed: 2023-03-29 - Published: 2023-08-03 - Granted: 2024-12-31 - Earliest claimed: 2020-09-30 - Assignees: FUJIFILM Corporation - Applicants: FUJIFILM Corporation - Inventors: Takashi Yonemoto; Yukito Saitoh; Hiroshi Sato - Web page: https://patentgrep.com/patent/US12181771B2 ## CPC - G02F 1/292: {by controlled diffraction or phased-array beam steering (controlled diffraction for optical switching G02F1/31)} - G02B 5/18: Diffraction gratings {(holographic optical elements G02B5/32, G03H; integrally combined with optical fibres G02B6/02057; for coupling light guides G02B6/34; integrally combined with optical integrated light guides G02B6/12; grating systems G02B27/44)} - G02B 5/1828: {having means for producing variable diffraction (controlling the direction of light by means of one or more diffracting elements G02B26/0808; acousto-optical elements G02F1/11, G02F1/33; electro- or magneto-optical diffraction G02F1/292, G02F1/2955)} - G02B 5/1833: {comprising birefringent materials (birefringent elements per se G02B5/3083)} - G02B 5/30: Polarising elements (light-modulating devices with active elements G02F1/00) - G02B 5/3016: {involving passive liquid crystal elements (optical properties of liquid crystals G02F1/0063; polarising elements associated with active liquid crystal devices G02F1/133528)} - G02F 1/1335: Structural association of cells with optical devices, e.g. polarisers or reflectors - G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS - G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS ## Abstract Provided is a transmissive liquid crystal diffraction element having a large diffraction angle and a high diffraction efficiency. The transmissive liquid crystal diffraction element includes a plurality of optically-anisotropic layers that are formed of a liquid crystal composition including a liquid crystal compound in a thickness direction, in which the optically-anisotropic layer has a liquid crystal alignment pattern in which a direction of an optical axis derived from the liquid crystal compound changes while continuously rotating in at least one in-plane direction, the one in-plane directions of the plurality of optically-anisotropic layers are parallel to each other, in two optically-anisotropic layers adjacent to each other among the plurality of optically-anisotropic layers, a rotation direction of the optical axis in the liquid crystal alignment pattern of one optically-anisotropic layer and a rotation direction of the optical axis in the liquid crystal alignment pattern of the other optically-anisotropic layer are opposite to each other, in cross-sectional images of the plurality of optically-anisotropic layers obtained by observing cross-sections taken in a thickness direction parallel to the one in-plane direction with a scanning electron microscope, the plurality of optically-anisotropic layers have bright portions and dark portions extending from one surface to another surface, and tilt angles of the dark portions of the plurality of optically-anisotropic layers change in order in the thickness direction. ## Claims ### Claim 1 A transmissive liquid crystal diffraction element comprising: a plurality of optically-anisotropic layers that are formed of a liquid crystal composition including a liquid crystal compound in a thickness direction, wherein the optically-anisotropic layer has a liquid crystal alignment pattern in which a direction of an optical axis derived from the liquid crystal compound changes while continuously rotating in at least one in-plane direction, the one in-plane directions of the plurality of optically-anisotropic layers are parallel to each other, in at least two optically-anisotropic layers adjacent to each other among the plurality of optically-anisotropic layers, a rotation direction of the optical axis in the liquid crystal alignment pattern of one optically-anisotropic layer and a rotation direction of the optical axis in the liquid crystal alignment pattern of the other optically-anisotropic layer are opposite to each other, in cross-sectional images of the plurality of optically-anisotropic layers obtained by observing cross-sections taken in a thickness direction parallel to the one in-plane direction with a scanning electron microscope, the plurality of optically-anisotropic layers have bright portions and dark portions extending from one surface to another surface, tilt angles of the dark portions of the plurality of optically-anisotropic layers change in order in the thickness direction, in at least one of the plurality of optically-anisotropic layers, the liquid crystal compound is twisted and aligned in the thickness direction, and twisted angle in the thickness direction is less than 360 degrees, and an in-plane retardation Δn×d of each of the plurality of optically-anisotropic layers satisfies 0.7×(λ/2)nm≤Δnλ×d≤1.3×(λ/2) nm, where λ represents a wavelength of an incident light. ### Claim 2 (depends on 1) The transmissive liquid crystal diffraction element according to claim 1, wherein tilt directions of the dark portions of the plurality of optically-anisotropic layers are the same as each other. ### Claim 3 (depends on 1) The transmissive liquid crystal diffraction element according to claim 1, wherein the dark portions of the plurality of optically-anisotropic layers consist of dark portions perpendicular to a main surface of the optically-anisotropic layers and dark portions tilted in the one in-plane direction. ### Claim 4 (depends on 1) The transmissive liquid crystal diffraction element according to claim 1, wherein the liquid crystal compound is a rod-like liquid crystal compound or a disk-like liquid crystal compound. ### Claim 5 (depends on 1) The transmissive liquid crystal diffraction element according to claim 1, wherein at least one of the plurality of optically-anisotropic layers has a configuration in which a rod-like liquid crystal layer where a rod-like liquid crystal compound is aligned in the liquid crystal alignment pattern and a disk-like liquid crystal layer where a disk-like liquid crystal compound is aligned in the liquid crystal alignment pattern are alternately laminated. ### Claim 6 (depends on 1) The transmissive liquid crystal diffraction element according to claim 1, wherein in at least one of the plurality of optically-anisotropic layers, the dark portion has one or more inflection points of angle. ### Claim 7 (depends on 1) The transmissive liquid crystal diffraction element according to claim 1, wherein the liquid crystal alignment pattern of the optically-anisotropic layer is a concentric circular pattern having a concentric circular shape where the one in-plane direction in which the direction of the optical axis derived from the liquid crystal compound changes while continuously rotating moves from an inner side toward an outer side. ### Claim 8 (depends on 1) The transmissive liquid crystal diffraction element according to claim 1, wherein in at least one of the plurality of optically-anisotropic layers, the tilt angles of the dark portions gradually change in the one in-plane direction. ### Claim 9 (depends on 1) The transmissive liquid crystal diffraction element according to claim 1, wherein one of the two optically-anisotropic layers adjacent to each other diffracts incident circularly polarized light and converts the rotation direction to another rotation direction opposite to the rotation direction, the circularly polarized light in which the rotation direction is converted to the another rotation direction is incident on another of the two optically anisotropic layer adjacent to each other, and the another of the two optically anisotropic layer adjacent to each other diffracts the circularly polarized light and converts the another direction to the rotation direction.