# US 12,181,693 B2 · Image capturing system with wavelength-selective energy scattering layer > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 12,181,693 B2 - Document ID: US12181693B2 - Status: Granted - Kind: B2 - Application number: 18/239,118 - Filed: 2023-08-28 - Published: 2023-12-21 - Granted: 2024-12-31 - Earliest claimed: 2015-04-14 - Assignees: Face International Corporation - Applicants: Face International Corporation - Inventors: Clark D Boyd; Bradbury R Face; Jeffrey D Shepard - Web page: https://patentgrep.com/patent/US12181693B2 ## CPC - C09D 5/006: {Anti-reflective coatings} - G02B 5/0294: {adapted to provide an additional optical effect, e.g. anti-reflection or filter} - C09D 5/30: Camouflage paints - C09D 7/62: modified by treatment with other compounds - G02B 5/008: {Surface plasmon devices (diffractive gratings with a pitch less than or comparable to the wavelength G02B5/1809; surface plasmons in integrated optics G02B6/1226; optical analysis of materials by means of surface plasmons G01N21/553)} - G02B 5/0242: {by means of dispersed particles} - G02B 5/0289: {used as a transflector} - G02B 5/206: {comprising particles embedded in a solid matrix} - G02B 5/26: Reflecting filters (G02B5/28 takes precedence) - G02B 1/04: made of organic materials, e.g. plastics (G02B1/08 takes precedence) - C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D) - G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS ## Abstract A particularly-formed multi-layer micron-sized particle is provided that is substantially transparent, yet that exhibits selectable coloration based on its physical properties. The disclosed physical properties of the particle are controllably selectable refractive indices to provide an opaque-appearing energy transmissive material when pluralities of the particles are suspended in a substantially transparent matrix material. Multiply-layered (up to 30+ constituent layers) particles result in an overall particle diameter of less than 5 microns. The material suspensions render the particles deliverable as aspirated or aerosol compositions onto substrates to form layers that selectively scatter specific wavelengths of electromagnetic energy while allowing remaining wavelengths of the incident energy to pass. The disclosed particles and material compositions uniquely implement optical light scattering techniques in energy (or light) transmissive layers that appear selectively opaque, while allowing 80+% of the energy impinging on the light incident side to pass through the layers. ## Claims ### Claim 1 An image capturing system, comprising: an energy transmissive layer applied to a structure to produce a selectively colored surface that effectively camouflages an image device placed behind said structure; said energy transmissive layer comprising a plurality of substantially transparent particles, each particle comprising: a spherical core comprised of a first transparent dielectric material, the spherical core having a value of a physical diameter equal to a half wavelength of a first selected color of light component to be reflected by the particle modified by a refractive index of the first transparent dielectric material; a plurality of material layers disposed radially outwardly from the spherical core, each of the plurality of material layers being comprised of at least a second transparent dielectric material, and having a value of a physical thickness equal to a quarter wavelength of at least a second selected color of light component to be reflected by the particle modified by a refractive index of the at least the second transparent dielectric material; and an outer coating comprised of another transparent dielectric material having a selected index of refraction of 2 or less, the outer coating having a thickness that substantially eliminates reflective interference between the colors reflected by adjacent particles when in contact with one another; wherein said plurality of substantially transparent particles are suspended in a substantially transparent binder material forming said energy transmissive layer. ### Claim 2 (depends on 1) The image capturing system of claim 1, the plurality of material layers being disposed on the spherical core in a layer-by-layer deposition process. ### Claim 3 (depends on 2) The image capturing system of claim 2, the layer-by-layer deposition process comprising an atomic layer deposition (ALD) process. ### Claim 4 (depends on 1) The image capturing system of claim 1, the first selected color of light component being a substantially same color as the second selected color of light component. ### Claim 5 (depends on 1) The image capturing system of claim 1, the first selected color of light component being a different color than the second selected color of light component. ### Claim 6 (depends on 1) The image capturing system of claim 1, the first transparent dielectric material being a same dielectric material as one of the at least the second transparent dielectric material. ### Claim 7 (depends on 1) The image capturing system of claim 1, the at least the second transparent dielectric material having an optical band gap greater than a photon energy of the at least the second selected color of light component. ### Claim 8 (depends on 1) The image capturing system of claim 1, the at least the second transparent dielectric material comprising a first transparent layer dielectric material and a second transparent layer dielectric material, adjacent layers of the plurality of material layers being formed alternatively of the first transparent layer dielectric material and the second transparent dielectric material. ### Claim 9 (depends on 1) The energy harvesting system of claim 1, the plurality of material layers comprising at least 15 material layers. ### Claim 10 (depends on 1) The energy harvesting system of claim 1, the plurality of material layers comprising at least 30 material layers. ### Claim 11 (depends on 1) The energy harvesting system of claim 1, the particle having an overall particle size of less than 5 microns. ### Claim 12 (depends on 1) The energy harvesting system of claim 1, the particle having an overall particle size in a range of 1.9 to 2.6 microns. ### Claim 13 (depends on 1) The image capturing system of claim 1, the first transparent dielectric material and the at least the second transparent dielectric material being selected from a group consisting of titanium dioxide, silicon carbide, sulfur, boron nitride, boron arsenite, aluminum nitride, aluminum phosphide, gallium nitride, gallium phosphide, cadmium sulfide, zinc oxide, zinc selenide, zinc sulfide, zinc telluride, cuprous chloride, tin dioxide, barium titanate, strontium titanate, lithium niobate, and nickel oxide. ### Claim 14 (depends on 1) The image capturing system of claim 1, further comprising a plurality of metallic material layers sandwiched between at least some adjacent pairs of material layers. ### Claim 15 (depends on 14) The image capturing system of claim 14, each of the plurality of metallic material layers being between 0.01 nm and 10 nm thick. ### Claim 16 (depends on 15) The image capturing system of claim 15, at least one of the plurality of metallic material layers being formed of indium titanium oxide (ITO). ### Claim 17 (depends on 1) The image capturing system of claim 1, wherein said substantially transparent binder material is characterized by having an index of refraction equal to the selected index of refraction of the outer coating. ### Claim 18 (depends on 1) The image capturing system of claim 1, the substantially transparent binder material being selected from a group consisting of synthetic or natural resins, alkyds, acrylics, vinyl-acrylics, vinyl acetate/ethylene (VAE), polyurethanes, polyesters, melamine resins, epoxy, and silanes or siloxanes. ### Claim 19 (depends on 1) The image capturing system of claim 1, the substantially transparent binder material comprising an adhesive that facilitates adherence of the material composition to a surface.