Polyorganosiloxane composition for use in adhesion of a polyphenylene sulfide resin
AssigneeMomentive Performance Materials Japan LLC
InventorMasanori Takanashi
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Abstract
An addition reaction curing type polyorganosiloxane composition for bonding poly(phenylene sulfide) resins includes (A) a polyorganosiloxane containing two or more alkenyl groups in the molecule, (B) a polyorganohydrogensiloxane having, in the molecule, three or more silicon-atom-bonded hydrogen atoms, (C) a platinum-based catalyst, (D) an oxide or carbonate of a metal selected from among the metals in Groups 2 and 12 of the periodic table, and (E) an adhesion promoter, the content of the ingredient (D) being 0.1-20 wt % with respect to the whole composition.
Claims8
A method of adhering a polyphenylene sulfide resin and a cured product of a polyorganosiloxane composition, the method comprising:
- applying the polyorganosiloxane composition to the polyphenylene sulfide resin;
- and
- curing the polyorganosiloxane composition;
- wherein the polyorganosiloxane composition comprises:
- (A) a polyorganosiloxane containing two or more alkenyl groups per molecule;
- (B) a polyorganohydrogensiloxane having three or more hydrogen atoms bonded to silicon atoms per molecule;
- (C) a platinum catalyst;
- (D) an oxide or carbonate of a metal selected from metals belonging to Groups 2 and 12 of the Periodic Table;
- and
- (E) an adhesion imparting agent,
- wherein the content of the component (D) in the whole composition is 0.1 to 20% by weight,
- wherein the component (D) is selected from the group consisting of magnesium oxide, calcium carbonate, and zinc oxide, and
- wherein the component (A) is a combination of (A1) a linear polyorganosiloxane having both ends blocked by an R3SiO1/2 unit and having an R22SiO2/2 unit as an intermediate unit, and having a viscosity of 0.1 to 500 Pas at 23° C., and (A2) a branched polyorganosiloxane comprising an SiO4/2 unit and an R3SiO1/2 unit and optionally further comprising at least one unit selected from the group consisting of an R2SiO2/2 unit and/or an RSiO3/2 unit, wherein, in the above formulae, R is R1 or R2, wherein R1 is an alkenyl group, R2 is a monovalent hydrocarbon group having no aliphatic unsaturated bond, and two or more R1's are contained per molecule.
Dependencies are inferred from the claim text.