# US 12,180,076 B2 · Method for preparing expanded foamed graphite film

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 12,180,076 B2
- Document ID: US12180076B2
- Status: Granted
- Kind: B2
- Application number: 18/613,339
- Filed: 2024-03-22
- Published: 2024-10-31
- Granted: 2024-12-31
- Earliest claimed: 2023-04-25
- Assignees: Guangdong Suqun New Material Co., Ltd
- Applicants: GuangDong Suqun New Material Co., Ltd
- Inventors: Zhoujie Gu; Teng Lv; Xiaoyong Guo; Hao Wang; Zeming Ren
- Web page: https://patentgrep.com/patent/US12180076B2

## CPC

- C01B 32/225: Expansion; Exfoliation
- C01B 32/205: Preparation
- C01P 2004/03: obtained by SEM
- C01P 2006/32: Thermal properties
- Y02E 60/10: Energy storage using batteries
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- C01P: INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A method for preparing expanded foamed graphite film includes the following steps: Step A: impregnating a synthetic graphite film into an intercalator for an interlayer intercalation treatment to prepare an intercalated graphite film; Step B: performing a thickness-limited expansion and foaming to the intercalated graphite film obtained in Step A, with an expansion ratio y of 2-25, to obtain an expanded foamed intercalated graphite film.

## Claims

### Claim 1

A method for preparing an expanded foamed graphite film, comprising the following steps:
Step A: impregnating a synthetic graphite film into an intercalator for an interlayer intercalation treatment to prepare an intercalated graphite film; and
Step B: performing a thickness-limited expansion and foaming to the intercalated graphite film obtained in the Step A, with an expansion ratio y of 2-25, to obtain an expanded foamed intercalated graphite film, wherein y=T2/T1, T1 refers to a first thickness of the intercalated graphite film obtained in the Step A, and T2 refers to a second thickness of the expanded foamed intercalated graphite film after the thickness-limited expansion and foaming;
wherein in the Step A, the intercalator comprises conductive particles, and the conductive particles account for 0.01-5% of a total mass of the intercalator;
wherein the conductive particles comprise one or more selected from the group consisting of boron nitride, boron carbide, silicon carbide, aluminum nitride, and silicon nitride.

### Claim 2 (depends on 1)

A method for preparing an expanded foamed graphite film according to claim 1, wherein in the Step A, a method for preparing the synthetic graphite film comprises the following steps: carbonizing and graphitizing a polyimide film successively to obtain the synthetic graphite film.

### Claim 3 (depends on 1)

A method for preparing an expanded foamed graphite film according to claim 1, wherein in the Step A, the intercalator further comprises one or more selected from the group consisting of hydrogen peroxide, ammonium persulfate, perchloric acid, concentrated sulfuric acid, acetic acid, phosphoric acid, concentrated nitric acid, and potassium permanganate.

### Claim 4 (depends on 1)

A method for preparing an expanded foamed graphite film according to claim 1, wherein in the Step B, the thickness-limited expansion and foaming is a high-temperature expansion treatment or a microwave expansion treatment; the high-temperature expansion treatment has a processing temperature of 300-1000° C. and a processing period of 0.2-5 min, and the microwave expansion treatment has a processing power of 500-5000 W and a processing period of 0.5-10 min.

### Claim 5 (depends on 1)

A method for preparing an expanded foamed graphite film according to claim 1, wherein in the Step A, the intercalator further comprises a metal salt, and the metal salt accounts for 0.01-5% of the total mass of the intercalator.

### Claim 6 (depends on 5)

A method for preparing an expanded foamed graphite film according to claim 5, wherein after the Step B, the method for preparing an expanded foamed graphite film further comprises Step C: performing a reduction treatment to the expanded foamed intercalated graphite film after the thickness-limited expansion and foaming of the Step B, under a reduction temperature of 500-1200° C.

### Claim 7 (depends on 1)

A method for preparing an expanded foamed graphite film according to claim 1, wherein the synthetic graphite film has an in-plane thermal conductivity of 100-1800 W/m·K, and a density of 0.3-2.2 g/cm3.

### Claim 8 (depends on 1)

A method for preparing an expanded foamed graphite film according to claim 1, wherein in the Step A, an impregnating period for the interlayer intercalation treatment is 0.5-60 min, and an impregnating temperature for the interlayer intercalation treatment is 10-50° C.

### Claim 9 (depends on 5)

A method for preparing an expanded foamed graphite film according to claim 5, wherein the metal salt comprises one or more selected from the group consisting of ferric chloride, copper chloride, zinc chloride, copper sulfate, copper nitrate, silver nitrate, ferric sulfate, ferrous sulfate, ferric nitrate, and nickel sulfate.