Phenylene ether oligomer composition
AssigneeShpp Global Technologies B.V.
InventorsDouglas Henry Lenz, Madhav Ghanta, Matias Bikel
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Abstract
A phenylene ether oligomer composition is disclosed comprising, a phenylene ether oligomer having an external amine content of less than or equal to 1.5 weight percent; and a residual solvent in an amount of 10 to 10000 parts per million by weight, based on the weight of the phenylene ether oligomer composition; wherein the phenylene ether oligomer composition has an intrinsic viscosity of 0.03 to 0.13 deciliter per gram; a glass transition temperature of 135 to 175° C., or a combination thereof.
Claims18
A phenylene ether oligomer composition comprising,
- a phenylene ether oligomer having an external amine content of greater than 0 to less than or equal to 1.3 weight percent;
- and
- wherein the phenylene ether oligomer composition has a residual solvent in an amount of 10 to 10,000 parts per million by weight, based on the weight of the phenylene ether oligomer composition;
- wherein the external amine has a formula
- wherein:
- Z1 is halogen, unsubstituted or substituted C1-C12 hydrocarbyl provided that the hydrocarbyl group is not tertiary hydrocarbyl, C1-C12 hydrocarbylthio, C1-C12 hydrocarbyloxy, or C2-C12 halohydrocarbyloxy wherein at least two carbon atoms separate the halogen and oxygen atoms;
- each occurrence of Z2 is independently hydrogen, halogen, unsubstituted or substituted C1-C12 hydrocarbyl provided that the hydrocarbyl group is not tertiary hydrocarbyl, C1-C12 hydrocarbylthio, C1-C12 hydrocarbyloxy, or C2-C12 halohydrocarbyloxy wherein at least two carbon atoms separate the halogen and oxygen atoms;
- each occurrence of R1 is independently hydrogen or unsubstituted or substituted C1-C12 hydrocarbyl;
- and
- each occurrence of R2 is independently an unsubstituted or substituted C1-C12 hydrocarbyl;
- wherein the phenylene ether oligomer composition has
- an intrinsic viscosity of 0.03 to 0.13 deciliter per gram;
- a glass transition temperature of 135 to 175° C.;
- or
- a combination thereof.
A phenylene ether oligomer composition comprising,
- a phenylene ether oligomer having an external amine content of greater than 0 to less than or equal to 1.3 weight percent;
- and
- a residual solvent in an amount of 10 to 10000 parts per million by weight, based on the weight of the phenylene ether oligomer composition;
- wherein the phenylene ether oligomer composition has a zero shear melt viscosity of 20,000 to 100,000 centipoise at 200° C. and an intrinsic viscosity of 0.03 to 0.13 deciliter per gram.
Dependencies are inferred from the claim text.